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Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method. / Kornyakov, Ilya V.; Krivovichev, Sergey V.; Gurzhiy, Vladislav V.

в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 644, № 2, 01.02.2018, стр. 77-81.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kornyakov, IV, Krivovichev, SV & Gurzhiy, VV 2018, 'Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method', Zeitschrift fur Anorganische und Allgemeine Chemie, Том. 644, № 2, стр. 77-81. https://doi.org/10.1002/zaac.201700342

APA

Kornyakov, I. V., Krivovichev, S. V., & Gurzhiy, V. V. (2018). Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method. Zeitschrift fur Anorganische und Allgemeine Chemie, 644(2), 77-81. https://doi.org/10.1002/zaac.201700342

Vancouver

Kornyakov IV, Krivovichev SV, Gurzhiy VV. Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method. Zeitschrift fur Anorganische und Allgemeine Chemie. 2018 Февр. 1;644(2):77-81. https://doi.org/10.1002/zaac.201700342

Author

Kornyakov, Ilya V. ; Krivovichev, Sergey V. ; Gurzhiy, Vladislav V. / Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method. в: Zeitschrift fur Anorganische und Allgemeine Chemie. 2018 ; Том 644, № 2. стр. 77-81.

BibTeX

@article{3f0ee8688f2341bc9c7b055892467762,
title = "Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method",
abstract = "Three novel copper compounds, Rb4Cu4OCl10 (I), Rb[Cu3O](SeO3)2Cl (II), and RbCu3(OH)(SeO3)Cl4(H2O)3 (III) were prepared by chemical vapor transport (CVT) reactions method from mixtures of CuO, SeO2, RbCl, and CuCl2. The crystal structures of the three compounds were determined by direct methods. Compound I is a Rb analogue of ponomarevite, K4Cu4OCl10. Its crystal structure contains {[OCu4]Cl10}4– clusters with oxocentered [OCu4]6+ tetrahedra as cores. The clusters are linked by the Rb+ cations. The crystal structure of II contains complex {[O2Cu6](SeO3)4Cl2}2– layers formed by dimers of edge-sharing [OCu4]6+ tetrahedra interlinked via selenite groups and Cl– anions. The crystal structure of III is based upon {[(OH)Cu3](SeO3)}3+ layers formed by the [(OH)Cu3]5+ tetrahedra attached to (SeO3)2– groups. The layers are linked via Cl– anions and via hydrogen bonds to H2O molecules.",
keywords = "Chemical vapor transport reactions, Copper, Minerals, Oxocentered tetrahedra, Structure elucidation",
author = "Kornyakov, {Ilya V.} and Krivovichev, {Sergey V.} and Gurzhiy, {Vladislav V.}",
year = "2018",
month = feb,
day = "1",
doi = "10.1002/zaac.201700342",
language = "English",
volume = "644",
pages = "77--81",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",
number = "2",

}

RIS

TY - JOUR

T1 - Oxocentered Units in Three Novel Rb-Containing Copper Compounds Prepared by CVT Reaction Method

AU - Kornyakov, Ilya V.

AU - Krivovichev, Sergey V.

AU - Gurzhiy, Vladislav V.

PY - 2018/2/1

Y1 - 2018/2/1

N2 - Three novel copper compounds, Rb4Cu4OCl10 (I), Rb[Cu3O](SeO3)2Cl (II), and RbCu3(OH)(SeO3)Cl4(H2O)3 (III) were prepared by chemical vapor transport (CVT) reactions method from mixtures of CuO, SeO2, RbCl, and CuCl2. The crystal structures of the three compounds were determined by direct methods. Compound I is a Rb analogue of ponomarevite, K4Cu4OCl10. Its crystal structure contains {[OCu4]Cl10}4– clusters with oxocentered [OCu4]6+ tetrahedra as cores. The clusters are linked by the Rb+ cations. The crystal structure of II contains complex {[O2Cu6](SeO3)4Cl2}2– layers formed by dimers of edge-sharing [OCu4]6+ tetrahedra interlinked via selenite groups and Cl– anions. The crystal structure of III is based upon {[(OH)Cu3](SeO3)}3+ layers formed by the [(OH)Cu3]5+ tetrahedra attached to (SeO3)2– groups. The layers are linked via Cl– anions and via hydrogen bonds to H2O molecules.

AB - Three novel copper compounds, Rb4Cu4OCl10 (I), Rb[Cu3O](SeO3)2Cl (II), and RbCu3(OH)(SeO3)Cl4(H2O)3 (III) were prepared by chemical vapor transport (CVT) reactions method from mixtures of CuO, SeO2, RbCl, and CuCl2. The crystal structures of the three compounds were determined by direct methods. Compound I is a Rb analogue of ponomarevite, K4Cu4OCl10. Its crystal structure contains {[OCu4]Cl10}4– clusters with oxocentered [OCu4]6+ tetrahedra as cores. The clusters are linked by the Rb+ cations. The crystal structure of II contains complex {[O2Cu6](SeO3)4Cl2}2– layers formed by dimers of edge-sharing [OCu4]6+ tetrahedra interlinked via selenite groups and Cl– anions. The crystal structure of III is based upon {[(OH)Cu3](SeO3)}3+ layers formed by the [(OH)Cu3]5+ tetrahedra attached to (SeO3)2– groups. The layers are linked via Cl– anions and via hydrogen bonds to H2O molecules.

KW - Chemical vapor transport reactions

KW - Copper

KW - Minerals

KW - Oxocentered tetrahedra

KW - Structure elucidation

UR - http://www.scopus.com/inward/record.url?scp=85041137964&partnerID=8YFLogxK

U2 - 10.1002/zaac.201700342

DO - 10.1002/zaac.201700342

M3 - Article

AN - SCOPUS:85041137964

VL - 644

SP - 77

EP - 81

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 2

ER -

ID: 18529916