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Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2. / Sandzhieva, M. A.; Aryamova, E. S.; Sukharzhevskii, S. M.; Grinenko, E. V.; Vasilyev, A. V.

в: Russian Journal of Organic Chemistry, Том 54, № 3, 01.03.2018, стр. 397-402.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Sandzhieva, MA, Aryamova, ES, Sukharzhevskii, SM, Grinenko, EV & Vasilyev, AV 2018, 'Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2', Russian Journal of Organic Chemistry, Том. 54, № 3, стр. 397-402. https://doi.org/10.1134/S1070428018030053

APA

Sandzhieva, M. A., Aryamova, E. S., Sukharzhevskii, S. M., Grinenko, E. V., & Vasilyev, A. V. (2018). Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2. Russian Journal of Organic Chemistry, 54(3), 397-402. https://doi.org/10.1134/S1070428018030053

Vancouver

Sandzhieva MA, Aryamova ES, Sukharzhevskii SM, Grinenko EV, Vasilyev AV. Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2. Russian Journal of Organic Chemistry. 2018 Март 1;54(3):397-402. https://doi.org/10.1134/S1070428018030053

Author

Sandzhieva, M. A. ; Aryamova, E. S. ; Sukharzhevskii, S. M. ; Grinenko, E. V. ; Vasilyev, A. V. / Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2. в: Russian Journal of Organic Chemistry. 2018 ; Том 54, № 3. стр. 397-402.

BibTeX

@article{05be5430a2344f6eba7fbe81a4971fa4,
title = "Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2",
abstract = "The oxidation of mono- and diiodo- and -bromo-substituted polymethylbenzenes (mesitylene and durene) in the system PbO2–CF3COOH–CH2Cl2 at room temperature (2–70 h) leads mainly to the formation of iodo- and bromobenzyl alcohols as result of oxidation of methyl group. The reaction involves intermediate formation of haloarene radical cations. ESR study of these radical cations made it possible to determine the structure of their singly occupied molecular orbitals a2 or b1 and interpret their reactivity.",
author = "Sandzhieva, {M. A.} and Aryamova, {E. S.} and Sukharzhevskii, {S. M.} and Grinenko, {E. V.} and Vasilyev, {A. V.}",
year = "2018",
month = mar,
day = "1",
doi = "10.1134/S1070428018030053",
language = "English",
volume = "54",
pages = "397--402",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "3",

}

RIS

TY - JOUR

T1 - Oxidation of Iodo- and Bromo-Substituted Polymethylbenzenes in the System PbO2–CF3COOH–CH2Cl2

AU - Sandzhieva, M. A.

AU - Aryamova, E. S.

AU - Sukharzhevskii, S. M.

AU - Grinenko, E. V.

AU - Vasilyev, A. V.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The oxidation of mono- and diiodo- and -bromo-substituted polymethylbenzenes (mesitylene and durene) in the system PbO2–CF3COOH–CH2Cl2 at room temperature (2–70 h) leads mainly to the formation of iodo- and bromobenzyl alcohols as result of oxidation of methyl group. The reaction involves intermediate formation of haloarene radical cations. ESR study of these radical cations made it possible to determine the structure of their singly occupied molecular orbitals a2 or b1 and interpret their reactivity.

AB - The oxidation of mono- and diiodo- and -bromo-substituted polymethylbenzenes (mesitylene and durene) in the system PbO2–CF3COOH–CH2Cl2 at room temperature (2–70 h) leads mainly to the formation of iodo- and bromobenzyl alcohols as result of oxidation of methyl group. The reaction involves intermediate formation of haloarene radical cations. ESR study of these radical cations made it possible to determine the structure of their singly occupied molecular orbitals a2 or b1 and interpret their reactivity.

UR - http://www.scopus.com/inward/record.url?scp=85048157041&partnerID=8YFLogxK

U2 - 10.1134/S1070428018030053

DO - 10.1134/S1070428018030053

M3 - Article

AN - SCOPUS:85048157041

VL - 54

SP - 397

EP - 402

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 3

ER -

ID: 44002275