Standard

Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C. / Stepakova, L. V.; Skripkin, M. Yu; Korneeva, V. V.; Grigoriev, Ya M.; Burkov, K. A.

в: Russian Journal of General Chemistry, Том 79, № 6, 01.06.2009, стр. 1053-1056.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Stepakova, LV, Skripkin, MY, Korneeva, VV, Grigoriev, YM & Burkov, KA 2009, 'Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C', Russian Journal of General Chemistry, Том. 79, № 6, стр. 1053-1056. https://doi.org/10.1134/S1070363209060012

APA

Stepakova, L. V., Skripkin, M. Y., Korneeva, V. V., Grigoriev, Y. M., & Burkov, K. A. (2009). Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C. Russian Journal of General Chemistry, 79(6), 1053-1056. https://doi.org/10.1134/S1070363209060012

Vancouver

Stepakova LV, Skripkin MY, Korneeva VV, Grigoriev YM, Burkov KA. Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C. Russian Journal of General Chemistry. 2009 Июнь 1;79(6):1053-1056. https://doi.org/10.1134/S1070363209060012

Author

Stepakova, L. V. ; Skripkin, M. Yu ; Korneeva, V. V. ; Grigoriev, Ya M. ; Burkov, K. A. / Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C. в: Russian Journal of General Chemistry. 2009 ; Том 79, № 6. стр. 1053-1056.

BibTeX

@article{27402ba3477c4723bb171dbc357f52ab,
title = "Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C",
abstract = "A solution-solid equilibrium in ternary water-organic systems CuCl 2-L-H2O (L = dimethyl sulfoxide, N,N-dimethyl formamide, and acetonitrile) at 25°C was studied. The expansion of crystallization branches of individual solvates CuCl2•xL varies in parallel to the donor power of organic solvents. The existence of the mixed crystal-solvates CuCl2•2H2O•2(CH3)2SO, CuCl2•2H2O•2(CH3)2NCHO, CuCl2•H2O•(CH3)2NCHO, CuCl2•2H2O•CH3CN, and CuCl 2•3H2O•2CH3CN in the studied systems was proved. Various donor power of oxygen-containing solvents determines the composition of the first coordination sphere of the copper ion in the specified compounds: the coordination of the both solvents in the mixed crystal-solvates with DMF and the absence of water in the nearest environment of the copper(II) ions in the CuCl2•2H2O•2(CH3) 2SO compound.",
author = "Stepakova, {L. V.} and Skripkin, {M. Yu} and Korneeva, {V. V.} and Grigoriev, {Ya M.} and Burkov, {K. A.}",
year = "2009",
month = jun,
day = "1",
doi = "10.1134/S1070363209060012",
language = "English",
volume = "79",
pages = "1053--1056",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Organic solvent effect on the solution-solid phase equilibria in the systems CuCl2-L-H2O (L = DMSO, DMF, acetonitrile) at 25°C

AU - Stepakova, L. V.

AU - Skripkin, M. Yu

AU - Korneeva, V. V.

AU - Grigoriev, Ya M.

AU - Burkov, K. A.

PY - 2009/6/1

Y1 - 2009/6/1

N2 - A solution-solid equilibrium in ternary water-organic systems CuCl 2-L-H2O (L = dimethyl sulfoxide, N,N-dimethyl formamide, and acetonitrile) at 25°C was studied. The expansion of crystallization branches of individual solvates CuCl2•xL varies in parallel to the donor power of organic solvents. The existence of the mixed crystal-solvates CuCl2•2H2O•2(CH3)2SO, CuCl2•2H2O•2(CH3)2NCHO, CuCl2•H2O•(CH3)2NCHO, CuCl2•2H2O•CH3CN, and CuCl 2•3H2O•2CH3CN in the studied systems was proved. Various donor power of oxygen-containing solvents determines the composition of the first coordination sphere of the copper ion in the specified compounds: the coordination of the both solvents in the mixed crystal-solvates with DMF and the absence of water in the nearest environment of the copper(II) ions in the CuCl2•2H2O•2(CH3) 2SO compound.

AB - A solution-solid equilibrium in ternary water-organic systems CuCl 2-L-H2O (L = dimethyl sulfoxide, N,N-dimethyl formamide, and acetonitrile) at 25°C was studied. The expansion of crystallization branches of individual solvates CuCl2•xL varies in parallel to the donor power of organic solvents. The existence of the mixed crystal-solvates CuCl2•2H2O•2(CH3)2SO, CuCl2•2H2O•2(CH3)2NCHO, CuCl2•H2O•(CH3)2NCHO, CuCl2•2H2O•CH3CN, and CuCl 2•3H2O•2CH3CN in the studied systems was proved. Various donor power of oxygen-containing solvents determines the composition of the first coordination sphere of the copper ion in the specified compounds: the coordination of the both solvents in the mixed crystal-solvates with DMF and the absence of water in the nearest environment of the copper(II) ions in the CuCl2•2H2O•2(CH3) 2SO compound.

UR - http://www.scopus.com/inward/record.url?scp=68949160018&partnerID=8YFLogxK

U2 - 10.1134/S1070363209060012

DO - 10.1134/S1070363209060012

M3 - Article

AN - SCOPUS:68949160018

VL - 79

SP - 1053

EP - 1056

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 6

ER -

ID: 40043020