Standard

Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2. / Борисов, Артем Сергеевич; Сийдра, Олег Иоханнесович; Пимшин, Иван Дмитриевич; Чаркин, Дмитрий Олегович; Хольцхайд, Астрид.

в: Structural Chemistry, 08.02.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Борисов, АС, Сийдра, ОИ, Пимшин, ИД, Чаркин, ДО & Хольцхайд, А 2025, 'Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2.', Structural Chemistry. https://doi.org/10.1007/s11224-025-02450-5

APA

Борисов, А. С., Сийдра, О. И., Пимшин, И. Д., Чаркин, Д. О., & Хольцхайд, А. (2025). Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2. Structural Chemistry. https://doi.org/10.1007/s11224-025-02450-5

Vancouver

Борисов АС, Сийдра ОИ, Пимшин ИД, Чаркин ДО, Хольцхайд А. Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2. Structural Chemistry. 2025 Февр. 8. https://doi.org/10.1007/s11224-025-02450-5

Author

Борисов, Артем Сергеевич ; Сийдра, Олег Иоханнесович ; Пимшин, Иван Дмитриевич ; Чаркин, Дмитрий Олегович ; Хольцхайд, Астрид. / Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2. в: Structural Chemistry. 2025.

BibTeX

@article{94552a16ec1b42569e4492ce3cd46cfd,
title = "Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2.",
abstract = "Two new cesium copper oxosulfates, Cs4Cu7O3(SO4)6 (1) and Cs4Cu7O3(SO4)6[Cu0.2O0.2] (2) which can be considered as representatives of the Cs4Cu7+xO3+x(SO4)6 series with x = 0 and x = 0.2, were prepared in evacuated silica tubes. Both compounds are triclinic, P1¯ and contain complex polynuclear ensembles of edge-sharing OCu4 tetrahedra decorated by sulfate anions; these building units are arranged into pseudo-layers. The partially disordered Cs+ cations fill the interstices in the structure. The overall topology of the two structures is very similar; however, in 2, the copper-oxide ensembles are additionally stitched by weakly occupied Cu–O fragments into pseudo-chains; this also results in essential disorder in the Cs sublattice. Both structures have very much in common with those of the puninite-euchlorine-fedotovite morphotropic series. We analyze the crystal chemical trends in this morphotropic series.",
keywords = "Cesium, Copper sulfate, Polynuclear ensembles, Puninite, Structural topology",
author = "Борисов, {Артем Сергеевич} and Сийдра, {Олег Иоханнесович} and Пимшин, {Иван Дмитриевич} and Чаркин, {Дмитрий Олегович} and Астрид Хольцхайд",
year = "2025",
month = feb,
day = "8",
doi = "10.1007/s11224-025-02450-5",
language = "English",
journal = "Structural Chemistry",
issn = "1040-0400",
publisher = "Springer Nature",

}

RIS

TY - JOUR

T1 - Order vs. disorder in puninite morphotropic series: synthesis and crystal structures of Cs4Cu7+xO3+x(SO4)6 with x = 0 and x = 0.2.

AU - Борисов, Артем Сергеевич

AU - Сийдра, Олег Иоханнесович

AU - Пимшин, Иван Дмитриевич

AU - Чаркин, Дмитрий Олегович

AU - Хольцхайд, Астрид

PY - 2025/2/8

Y1 - 2025/2/8

N2 - Two new cesium copper oxosulfates, Cs4Cu7O3(SO4)6 (1) and Cs4Cu7O3(SO4)6[Cu0.2O0.2] (2) which can be considered as representatives of the Cs4Cu7+xO3+x(SO4)6 series with x = 0 and x = 0.2, were prepared in evacuated silica tubes. Both compounds are triclinic, P1¯ and contain complex polynuclear ensembles of edge-sharing OCu4 tetrahedra decorated by sulfate anions; these building units are arranged into pseudo-layers. The partially disordered Cs+ cations fill the interstices in the structure. The overall topology of the two structures is very similar; however, in 2, the copper-oxide ensembles are additionally stitched by weakly occupied Cu–O fragments into pseudo-chains; this also results in essential disorder in the Cs sublattice. Both structures have very much in common with those of the puninite-euchlorine-fedotovite morphotropic series. We analyze the crystal chemical trends in this morphotropic series.

AB - Two new cesium copper oxosulfates, Cs4Cu7O3(SO4)6 (1) and Cs4Cu7O3(SO4)6[Cu0.2O0.2] (2) which can be considered as representatives of the Cs4Cu7+xO3+x(SO4)6 series with x = 0 and x = 0.2, were prepared in evacuated silica tubes. Both compounds are triclinic, P1¯ and contain complex polynuclear ensembles of edge-sharing OCu4 tetrahedra decorated by sulfate anions; these building units are arranged into pseudo-layers. The partially disordered Cs+ cations fill the interstices in the structure. The overall topology of the two structures is very similar; however, in 2, the copper-oxide ensembles are additionally stitched by weakly occupied Cu–O fragments into pseudo-chains; this also results in essential disorder in the Cs sublattice. Both structures have very much in common with those of the puninite-euchlorine-fedotovite morphotropic series. We analyze the crystal chemical trends in this morphotropic series.

KW - Cesium

KW - Copper sulfate

KW - Polynuclear ensembles

KW - Puninite

KW - Structural topology

UR - https://link.springer.com/article/10.1007/s11224-025-02450-5

UR - https://www.mendeley.com/catalogue/03b253b8-c7ef-3cdd-b556-60a8b084f831/

U2 - 10.1007/s11224-025-02450-5

DO - 10.1007/s11224-025-02450-5

M3 - Article

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

ER -

ID: 132248766