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Opening the Third Century of Polyhalide Chemistry : Thermally Stable Complex with “Trapped” Dichlorine. / Usoltsev, Andrey N.; Adonin, Sergey A.; Kolesov, Boris A.; Novikov, Alexander S.; Fedin, Vladimir P.; Sokolov, Maxim N.

в: Chemistry - A European Journal, Том 26, № 61, 02.11.2020, стр. 13776-13778.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Usoltsev, AN, Adonin, SA, Kolesov, BA, Novikov, AS, Fedin, VP & Sokolov, MN 2020, 'Opening the Third Century of Polyhalide Chemistry: Thermally Stable Complex with “Trapped” Dichlorine', Chemistry - A European Journal, Том. 26, № 61, стр. 13776-13778. https://doi.org/10.1002/chem.202002014

APA

Usoltsev, A. N., Adonin, S. A., Kolesov, B. A., Novikov, A. S., Fedin, V. P., & Sokolov, M. N. (2020). Opening the Third Century of Polyhalide Chemistry: Thermally Stable Complex with “Trapped” Dichlorine. Chemistry - A European Journal, 26(61), 13776-13778. https://doi.org/10.1002/chem.202002014

Vancouver

Usoltsev AN, Adonin SA, Kolesov BA, Novikov AS, Fedin VP, Sokolov MN. Opening the Third Century of Polyhalide Chemistry: Thermally Stable Complex with “Trapped” Dichlorine. Chemistry - A European Journal. 2020 Нояб. 2;26(61):13776-13778. https://doi.org/10.1002/chem.202002014

Author

Usoltsev, Andrey N. ; Adonin, Sergey A. ; Kolesov, Boris A. ; Novikov, Alexander S. ; Fedin, Vladimir P. ; Sokolov, Maxim N. / Opening the Third Century of Polyhalide Chemistry : Thermally Stable Complex with “Trapped” Dichlorine. в: Chemistry - A European Journal. 2020 ; Том 26, № 61. стр. 13776-13778.

BibTeX

@article{879bc668f3c14e94bc567e33a9bfbadb,
title = "Opening the Third Century of Polyhalide Chemistry: Thermally Stable Complex with “Trapped” Dichlorine",
abstract = "Unlike polyhalides of heavier halogens, polychlorides still remain exotic curiosities. Herein, we report preparation and investigation of complexes Cat2{[TeCl6](Cl2)} (cat=1-methylpyridinium (1) and tetramethylammonium (2)) where dichlorine units are “trapped” by chlorotellurate(IV) anions via a system of non-covalent Cl⋅⋅⋅Cl interactions. Complex 2 reveals a record thermal stability (>100 °C) for inclusion compounds with Cl2, indications that such compounds can be used as solid Cl2 source.",
keywords = "chlorine, halide complexes, halogen bonding, non-covalent interactions, supramolecular compounds, MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, COMPOUND, NONABROMOANTIMONATE(V), CL-35 NQR, BROMINE, RADII, X-RAY, STRUCTURAL PROOF, LIQUID-BASED SYNTHESIS",
author = "Usoltsev, {Andrey N.} and Adonin, {Sergey A.} and Kolesov, {Boris A.} and Novikov, {Alexander S.} and Fedin, {Vladimir P.} and Sokolov, {Maxim N.}",
note = "Funding Information: This work was supported by Russian Science Foundation (Grant No. 18–73–10040). Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = nov,
day = "2",
doi = "10.1002/chem.202002014",
language = "English",
volume = "26",
pages = "13776--13778",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "61",

}

RIS

TY - JOUR

T1 - Opening the Third Century of Polyhalide Chemistry

T2 - Thermally Stable Complex with “Trapped” Dichlorine

AU - Usoltsev, Andrey N.

AU - Adonin, Sergey A.

AU - Kolesov, Boris A.

AU - Novikov, Alexander S.

AU - Fedin, Vladimir P.

AU - Sokolov, Maxim N.

N1 - Funding Information: This work was supported by Russian Science Foundation (Grant No. 18–73–10040). Publisher Copyright: © 2020 Wiley-VCH GmbH Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/11/2

Y1 - 2020/11/2

N2 - Unlike polyhalides of heavier halogens, polychlorides still remain exotic curiosities. Herein, we report preparation and investigation of complexes Cat2{[TeCl6](Cl2)} (cat=1-methylpyridinium (1) and tetramethylammonium (2)) where dichlorine units are “trapped” by chlorotellurate(IV) anions via a system of non-covalent Cl⋅⋅⋅Cl interactions. Complex 2 reveals a record thermal stability (>100 °C) for inclusion compounds with Cl2, indications that such compounds can be used as solid Cl2 source.

AB - Unlike polyhalides of heavier halogens, polychlorides still remain exotic curiosities. Herein, we report preparation and investigation of complexes Cat2{[TeCl6](Cl2)} (cat=1-methylpyridinium (1) and tetramethylammonium (2)) where dichlorine units are “trapped” by chlorotellurate(IV) anions via a system of non-covalent Cl⋅⋅⋅Cl interactions. Complex 2 reveals a record thermal stability (>100 °C) for inclusion compounds with Cl2, indications that such compounds can be used as solid Cl2 source.

KW - chlorine

KW - halide complexes

KW - halogen bonding

KW - non-covalent interactions

KW - supramolecular compounds

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - COMPOUND

KW - NONABROMOANTIMONATE(V)

KW - CL-35 NQR

KW - BROMINE

KW - RADII

KW - X-RAY

KW - STRUCTURAL PROOF

KW - LIQUID-BASED SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85091805185&partnerID=8YFLogxK

U2 - 10.1002/chem.202002014

DO - 10.1002/chem.202002014

M3 - Article

AN - SCOPUS:85091805185

VL - 26

SP - 13776

EP - 13778

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 61

ER -

ID: 70760941