Standard

One-bond 13C-13C couplings in diacetylenes : Experimental and theoretical studies. / Kamieńska-Trela, Krystyna; Kania, Lidia; Schilf, Wojciech; Balova, Irina.

в: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Том 55, № 4, 1999, стр. 817-824.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kamieńska-Trela, K, Kania, L, Schilf, W & Balova, I 1999, 'One-bond 13C-13C couplings in diacetylenes: Experimental and theoretical studies', Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Том. 55, № 4, стр. 817-824. https://doi.org/10.1016/S1386-1425(98)00226-1

APA

Kamieńska-Trela, K., Kania, L., Schilf, W., & Balova, I. (1999). One-bond 13C-13C couplings in diacetylenes: Experimental and theoretical studies. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 55(4), 817-824. https://doi.org/10.1016/S1386-1425(98)00226-1

Vancouver

Kamieńska-Trela K, Kania L, Schilf W, Balova I. One-bond 13C-13C couplings in diacetylenes: Experimental and theoretical studies. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 1999;55(4):817-824. https://doi.org/10.1016/S1386-1425(98)00226-1

Author

Kamieńska-Trela, Krystyna ; Kania, Lidia ; Schilf, Wojciech ; Balova, Irina. / One-bond 13C-13C couplings in diacetylenes : Experimental and theoretical studies. в: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 1999 ; Том 55, № 4. стр. 817-824.

BibTeX

@article{727c961e91d54b18a161cba77076dd73,
title = "One-bond 13C-13C couplings in diacetylenes: Experimental and theoretical studies",
abstract = "Carbon-carbon spin-spin coupling constants across one bond have been measured in several mono and dialkyl substituted diacetylenes, in dialkyl substituted tetraacetylene and in trimethylsilyl substituted diacetylene. This provides new examples of the coupling constants across Csp-Csp single bonds, which, so far, have been determined for a very few compounds only. The semi-empirical INDO FPT calculations have been performed for mono substituted diacetylenes with substituents varying along the first row of the Periodical Table. The calculated results revealed that one-bond 13C-13C coupling constants across CC triple bonds with the substituent directly bound to the bond concerned as well as those across the central single CC bond are significantly affected by substituent effects.",
keywords = "C-C couplings, Diacetylenes, Experimental and theoretical studies",
author = "Krystyna Kamie{\'n}ska-Trela and Lidia Kania and Wojciech Schilf and Irina Balova",
year = "1999",
doi = "10.1016/S1386-1425(98)00226-1",
language = "English",
volume = "55",
pages = "817--824",
journal = "SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY",
issn = "1386-1425",
publisher = "Elsevier",
number = "4",

}

RIS

TY - JOUR

T1 - One-bond 13C-13C couplings in diacetylenes

T2 - Experimental and theoretical studies

AU - Kamieńska-Trela, Krystyna

AU - Kania, Lidia

AU - Schilf, Wojciech

AU - Balova, Irina

PY - 1999

Y1 - 1999

N2 - Carbon-carbon spin-spin coupling constants across one bond have been measured in several mono and dialkyl substituted diacetylenes, in dialkyl substituted tetraacetylene and in trimethylsilyl substituted diacetylene. This provides new examples of the coupling constants across Csp-Csp single bonds, which, so far, have been determined for a very few compounds only. The semi-empirical INDO FPT calculations have been performed for mono substituted diacetylenes with substituents varying along the first row of the Periodical Table. The calculated results revealed that one-bond 13C-13C coupling constants across CC triple bonds with the substituent directly bound to the bond concerned as well as those across the central single CC bond are significantly affected by substituent effects.

AB - Carbon-carbon spin-spin coupling constants across one bond have been measured in several mono and dialkyl substituted diacetylenes, in dialkyl substituted tetraacetylene and in trimethylsilyl substituted diacetylene. This provides new examples of the coupling constants across Csp-Csp single bonds, which, so far, have been determined for a very few compounds only. The semi-empirical INDO FPT calculations have been performed for mono substituted diacetylenes with substituents varying along the first row of the Periodical Table. The calculated results revealed that one-bond 13C-13C coupling constants across CC triple bonds with the substituent directly bound to the bond concerned as well as those across the central single CC bond are significantly affected by substituent effects.

KW - C-C couplings

KW - Diacetylenes

KW - Experimental and theoretical studies

UR - http://www.scopus.com/inward/record.url?scp=0343986741&partnerID=8YFLogxK

U2 - 10.1016/S1386-1425(98)00226-1

DO - 10.1016/S1386-1425(98)00226-1

M3 - Article

AN - SCOPUS:0343986741

VL - 55

SP - 817

EP - 824

JO - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

JF - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

SN - 1386-1425

IS - 4

ER -

ID: 96688784