Standard

On the structure and dynamics of heterovalently doped β-PbF2. / ten Eicken, J.; Gunsser, W.; Karus, M.; Meyer, A.; Murin, I. V.

в: Solid State Ionics, Том 72, № PART 2, 09.1994, стр. 7-11.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

ten Eicken, J, Gunsser, W, Karus, M, Meyer, A & Murin, IV 1994, 'On the structure and dynamics of heterovalently doped β-PbF2', Solid State Ionics, Том. 72, № PART 2, стр. 7-11. https://doi.org/10.1016/0167-2738(94)90117-1

APA

ten Eicken, J., Gunsser, W., Karus, M., Meyer, A., & Murin, I. V. (1994). On the structure and dynamics of heterovalently doped β-PbF2. Solid State Ionics, 72(PART 2), 7-11. https://doi.org/10.1016/0167-2738(94)90117-1

Vancouver

ten Eicken J, Gunsser W, Karus M, Meyer A, Murin IV. On the structure and dynamics of heterovalently doped β-PbF2. Solid State Ionics. 1994 Сент.;72(PART 2):7-11. https://doi.org/10.1016/0167-2738(94)90117-1

Author

ten Eicken, J. ; Gunsser, W. ; Karus, M. ; Meyer, A. ; Murin, I. V. / On the structure and dynamics of heterovalently doped β-PbF2. в: Solid State Ionics. 1994 ; Том 72, № PART 2. стр. 7-11.

BibTeX

@article{63fb3e7f10c145bbb1fe5ce6c489f5ba,
title = "On the structure and dynamics of heterovalently doped β-PbF2",
abstract = "Heterovalent isomorphous replacement is one of the main methods to increase the ionic conductivity of solid electrolytes. Understanding the nature of these impurity defects and their relaxation can help in establishing the connection between the electrophysical properties and crystallochemical peculiarities of doped superionic conductors. EPR spectra of Gd3+ in PbF2 show a well resolved fine structure as well as spin forbidden transitions with ΔMs>1. The angular dependence in both cases indicates that Gd3+ occupies a purely cubic symmetric site. This stands in contrast to earlier results and is indicative of the importance of the history of a sample, especially its thermal and pressure treatment, as shown by X-ray analysis and conductivity data. A method of investigating dipole defects and polarizing phenomena is proposed, whereby RE-Fi dipole defects are fixed and their relaxation is studied by means of EPR-spectroscopy.",
author = "{ten Eicken}, J. and W. Gunsser and M. Karus and A. Meyer and Murin, {I. V.}",
note = "Funding Information: We gratefully appreciate the support given to one of us (J.t.E.) by the Alfried Krupp von Bohlen und Halbach Stiftung.",
year = "1994",
month = sep,
doi = "10.1016/0167-2738(94)90117-1",
language = "English",
volume = "72",
pages = "7--11",
journal = "Solid State Ionics",
issn = "0167-2738",
publisher = "Elsevier",
number = "PART 2",

}

RIS

TY - JOUR

T1 - On the structure and dynamics of heterovalently doped β-PbF2

AU - ten Eicken, J.

AU - Gunsser, W.

AU - Karus, M.

AU - Meyer, A.

AU - Murin, I. V.

N1 - Funding Information: We gratefully appreciate the support given to one of us (J.t.E.) by the Alfried Krupp von Bohlen und Halbach Stiftung.

PY - 1994/9

Y1 - 1994/9

N2 - Heterovalent isomorphous replacement is one of the main methods to increase the ionic conductivity of solid electrolytes. Understanding the nature of these impurity defects and their relaxation can help in establishing the connection between the electrophysical properties and crystallochemical peculiarities of doped superionic conductors. EPR spectra of Gd3+ in PbF2 show a well resolved fine structure as well as spin forbidden transitions with ΔMs>1. The angular dependence in both cases indicates that Gd3+ occupies a purely cubic symmetric site. This stands in contrast to earlier results and is indicative of the importance of the history of a sample, especially its thermal and pressure treatment, as shown by X-ray analysis and conductivity data. A method of investigating dipole defects and polarizing phenomena is proposed, whereby RE-Fi dipole defects are fixed and their relaxation is studied by means of EPR-spectroscopy.

AB - Heterovalent isomorphous replacement is one of the main methods to increase the ionic conductivity of solid electrolytes. Understanding the nature of these impurity defects and their relaxation can help in establishing the connection between the electrophysical properties and crystallochemical peculiarities of doped superionic conductors. EPR spectra of Gd3+ in PbF2 show a well resolved fine structure as well as spin forbidden transitions with ΔMs>1. The angular dependence in both cases indicates that Gd3+ occupies a purely cubic symmetric site. This stands in contrast to earlier results and is indicative of the importance of the history of a sample, especially its thermal and pressure treatment, as shown by X-ray analysis and conductivity data. A method of investigating dipole defects and polarizing phenomena is proposed, whereby RE-Fi dipole defects are fixed and their relaxation is studied by means of EPR-spectroscopy.

UR - http://www.scopus.com/inward/record.url?scp=0028495297&partnerID=8YFLogxK

U2 - 10.1016/0167-2738(94)90117-1

DO - 10.1016/0167-2738(94)90117-1

M3 - Article

AN - SCOPUS:0028495297

VL - 72

SP - 7

EP - 11

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - PART 2

ER -

ID: 88061769