On the radiolytic stability of potentiometric sensors with plasticized polymeric membranes

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On the radiolytic stability of potentiometric sensors with plasticized polymeric membranes. / Savosina, Julia; Agafonova-Moroz, Marina; Khaydukova, Maria; Legin, Andrey; Babain, Vasiliy; Tolstoy, Peter ; Kirsanov, Dmitry.

в: Chemosensors, Том 9, № 8, 214, 08.08.2021.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Savosina, Julia ; Agafonova-Moroz, Marina ; Khaydukova, Maria ; Legin, Andrey ; Babain, Vasiliy ; Tolstoy, Peter ; Kirsanov, Dmitry. / On the radiolytic stability of potentiometric sensors with plasticized polymeric membranes. в: Chemosensors. 2021 ; Том 9, № 8.

BibTeX

@article{1837e53719d74e3387e748e65fb4b36b,

title = "On the radiolytic stability of potentiometric sensors with plasticized polymeric membranes",

abstract = "There is not much known on the stability of plasticized polymeric sensor membranes against ionizing radiation. While recent studies have indicated the applicability of potentiometric sensors with such membranes for quantification of actinides and lanthanides in spent nuclear fuel reprocessing solutions, the real industrial application of such sensors will require their stability in ionizing radiation fields. The present study explores this problem and evaluates the stability of potentiometric sensitivity towards lanthanides and actinides for a variety of plasticized polymeric membranes based on different neutral ligands. We demonstrate that most of the studied sensor compositions retain their sensitivity up to 50–100 kGy of the absorbed gamma radiation dose. The higher doses lead to the gradual loss of sensitivity due to the radiolysis of ligands and a polymer membrane matrix as confirmed by electrochemical impedance and nuclear magnetic resonance studies.",

keywords = "Actinides, Lantha-nides, Plasticized polymeric membranes, Potentiometric sensors, Radiolytic stability, Spent nuclear fuel, actinides, QUANTIFICATION, ELECTRODES, radiolytic stability, lanthanides, RADIATION-INDUCED DEGRADATION, STREAMS, potentiometric sensors, plasticized polymeric membranes, spent nuclear fuel",

author = "Julia Savosina and Marina Agafonova-Moroz and Maria Khaydukova and Andrey Legin and Vasiliy Babain and Peter Tolstoy and Dmitry Kirsanov",

note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = aug,

day = "8",

doi = "10.3390/chemosensors9080214",

language = "English",

volume = "9",

journal = "Chemosensors",

issn = "2227-9040",

publisher = "MDPI AG",

number = "8",

}

RIS

TY - JOUR

T1 - On the radiolytic stability of potentiometric sensors with plasticized polymeric membranes

AU - Savosina, Julia

AU - Agafonova-Moroz, Marina

AU - Khaydukova, Maria

AU - Legin, Andrey

AU - Babain, Vasiliy

AU - Tolstoy, Peter

AU - Kirsanov, Dmitry

PY - 2021/8/8

Y1 - 2021/8/8

N2 - There is not much known on the stability of plasticized polymeric sensor membranes against ionizing radiation. While recent studies have indicated the applicability of potentiometric sensors with such membranes for quantification of actinides and lanthanides in spent nuclear fuel reprocessing solutions, the real industrial application of such sensors will require their stability in ionizing radiation fields. The present study explores this problem and evaluates the stability of potentiometric sensitivity towards lanthanides and actinides for a variety of plasticized polymeric membranes based on different neutral ligands. We demonstrate that most of the studied sensor compositions retain their sensitivity up to 50–100 kGy of the absorbed gamma radiation dose. The higher doses lead to the gradual loss of sensitivity due to the radiolysis of ligands and a polymer membrane matrix as confirmed by electrochemical impedance and nuclear magnetic resonance studies.

AB - There is not much known on the stability of plasticized polymeric sensor membranes against ionizing radiation. While recent studies have indicated the applicability of potentiometric sensors with such membranes for quantification of actinides and lanthanides in spent nuclear fuel reprocessing solutions, the real industrial application of such sensors will require their stability in ionizing radiation fields. The present study explores this problem and evaluates the stability of potentiometric sensitivity towards lanthanides and actinides for a variety of plasticized polymeric membranes based on different neutral ligands. We demonstrate that most of the studied sensor compositions retain their sensitivity up to 50–100 kGy of the absorbed gamma radiation dose. The higher doses lead to the gradual loss of sensitivity due to the radiolysis of ligands and a polymer membrane matrix as confirmed by electrochemical impedance and nuclear magnetic resonance studies.

KW - Actinides

KW - Lantha-nides

KW - Plasticized polymeric membranes

KW - Potentiometric sensors

KW - Radiolytic stability

KW - Spent nuclear fuel

KW - actinides

KW - QUANTIFICATION

KW - ELECTRODES

KW - radiolytic stability

KW - lanthanides

KW - RADIATION-INDUCED DEGRADATION

KW - STREAMS

KW - potentiometric sensors

KW - plasticized polymeric membranes

KW - spent nuclear fuel

UR - http://www.scopus.com/inward/record.url?scp=85112761332&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/8e523224-61ff-35d2-a16b-e9c73a1313ad/

U2 - 10.3390/chemosensors9080214

DO - 10.3390/chemosensors9080214

M3 - Article

AN - SCOPUS:85112761332

VL - 9

JO - Chemosensors

JF - Chemosensors

SN - 2227-9040

IS - 8

M1 - 214

ER -

ID: 85204929