Результаты исследований: Научные публикации в периодических изданиях › статья
Novel type of molecular connectivity in one-dimensional uranyl compounds: [K(18-crown-6)(H2O)][(UO2)(SeO4)(NO 3)], a new potassium uranyl selenate with 18-crown-6 ether. / Gurzhiy, V.V.; Tyumentseva, O.S.; Krivovichev, S.V.; Tananaev, I.G.
в: Inorganic Chemistry Communications, Том 45, 2014, стр. 93-96.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Novel type of molecular connectivity in one-dimensional uranyl compounds: [K(18-crown-6)(H2O)][(UO2)(SeO4)(NO 3)], a new potassium uranyl selenate with 18-crown-6 ether
AU - Gurzhiy, V.V.
AU - Tyumentseva, O.S.
AU - Krivovichev, S.V.
AU - Tananaev, I.G.
PY - 2014
Y1 - 2014
N2 - New hybrid organic-inorganic uranyl selenate, [K(C12H 24O6)(H2O)][(UO2)(SeO 4)(NO3)] (I), has been prepared by a room-temperature evaporation from the aqueous solutions of uranyl nitrate, selenic acid, potassium nitrate and 18-crown-6 ether. The crystal structure of I [monoclinic, P21/c, a = 7.2404(2), b = 21.2024(7), c = 15.7322(5) Å, β = 91.5810(10)°, V = 2414.19(13) Å3, Z = 4, R1 = 0.023] is based upon the [(UO2)(SeO4)(NO 3)]- one-dimensional uranyl nitrate-selenate chains consisting of UO7 pentagonal bipyramids, SeO4 tetrahedra and nitrate groups. The chains are linked to the [K(18-crown-6)(H 2O)]+ complexes via the K+O bonds to form a "multi-axis transporter" {[K(18-crown-6)(H2O)][(UO 2)(SeO4)(NO3)]} bands that are linked together via weak hydrogen bonds only. The infrared spectroscopy data support the structural data. © 2014 Elsevier B.V.
AB - New hybrid organic-inorganic uranyl selenate, [K(C12H 24O6)(H2O)][(UO2)(SeO 4)(NO3)] (I), has been prepared by a room-temperature evaporation from the aqueous solutions of uranyl nitrate, selenic acid, potassium nitrate and 18-crown-6 ether. The crystal structure of I [monoclinic, P21/c, a = 7.2404(2), b = 21.2024(7), c = 15.7322(5) Å, β = 91.5810(10)°, V = 2414.19(13) Å3, Z = 4, R1 = 0.023] is based upon the [(UO2)(SeO4)(NO 3)]- one-dimensional uranyl nitrate-selenate chains consisting of UO7 pentagonal bipyramids, SeO4 tetrahedra and nitrate groups. The chains are linked to the [K(18-crown-6)(H 2O)]+ complexes via the K+O bonds to form a "multi-axis transporter" {[K(18-crown-6)(H2O)][(UO 2)(SeO4)(NO3)]} bands that are linked together via weak hydrogen bonds only. The infrared spectroscopy data support the structural data. © 2014 Elsevier B.V.
U2 - 10.1016/j.inoche.2014.04.012
DO - 10.1016/j.inoche.2014.04.012
M3 - Article
VL - 45
SP - 93
EP - 96
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -
ID: 7003713