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Novel type of molecular connectivity in one-dimensional uranyl compounds: [K(18-crown-6)(H2O)][(UO2)(SeO4)(NO 3)], a new potassium uranyl selenate with 18-crown-6 ether. / Gurzhiy, V.V.; Tyumentseva, O.S.; Krivovichev, S.V.; Tananaev, I.G.

в: Inorganic Chemistry Communications, Том 45, 2014, стр. 93-96.

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@article{9b9adf8357924e15bfe8f0071e9af5f7,
title = "Novel type of molecular connectivity in one-dimensional uranyl compounds: [K(18-crown-6)(H2O)][(UO2)(SeO4)(NO 3)], a new potassium uranyl selenate with 18-crown-6 ether",
abstract = "New hybrid organic-inorganic uranyl selenate, [K(C12H 24O6)(H2O)][(UO2)(SeO 4)(NO3)] (I), has been prepared by a room-temperature evaporation from the aqueous solutions of uranyl nitrate, selenic acid, potassium nitrate and 18-crown-6 ether. The crystal structure of I [monoclinic, P21/c, a = 7.2404(2), b = 21.2024(7), c = 15.7322(5) {\AA}, β = 91.5810(10)°, V = 2414.19(13) {\AA}3, Z = 4, R1 = 0.023] is based upon the [(UO2)(SeO4)(NO 3)]- one-dimensional uranyl nitrate-selenate chains consisting of UO7 pentagonal bipyramids, SeO4 tetrahedra and nitrate groups. The chains are linked to the [K(18-crown-6)(H 2O)]+ complexes via the K+O bonds to form a {"}multi-axis transporter{"} {[K(18-crown-6)(H2O)][(UO 2)(SeO4)(NO3)]} bands that are linked together via weak hydrogen bonds only. The infrared spectroscopy data support the structural data. {\textcopyright} 2014 Elsevier B.V.",
author = "V.V. Gurzhiy and O.S. Tyumentseva and S.V. Krivovichev and I.G. Tananaev",
year = "2014",
doi = "10.1016/j.inoche.2014.04.012",
language = "English",
volume = "45",
pages = "93--96",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Novel type of molecular connectivity in one-dimensional uranyl compounds: [K(18-crown-6)(H2O)][(UO2)(SeO4)(NO 3)], a new potassium uranyl selenate with 18-crown-6 ether

AU - Gurzhiy, V.V.

AU - Tyumentseva, O.S.

AU - Krivovichev, S.V.

AU - Tananaev, I.G.

PY - 2014

Y1 - 2014

N2 - New hybrid organic-inorganic uranyl selenate, [K(C12H 24O6)(H2O)][(UO2)(SeO 4)(NO3)] (I), has been prepared by a room-temperature evaporation from the aqueous solutions of uranyl nitrate, selenic acid, potassium nitrate and 18-crown-6 ether. The crystal structure of I [monoclinic, P21/c, a = 7.2404(2), b = 21.2024(7), c = 15.7322(5) Å, β = 91.5810(10)°, V = 2414.19(13) Å3, Z = 4, R1 = 0.023] is based upon the [(UO2)(SeO4)(NO 3)]- one-dimensional uranyl nitrate-selenate chains consisting of UO7 pentagonal bipyramids, SeO4 tetrahedra and nitrate groups. The chains are linked to the [K(18-crown-6)(H 2O)]+ complexes via the K+O bonds to form a "multi-axis transporter" {[K(18-crown-6)(H2O)][(UO 2)(SeO4)(NO3)]} bands that are linked together via weak hydrogen bonds only. The infrared spectroscopy data support the structural data. © 2014 Elsevier B.V.

AB - New hybrid organic-inorganic uranyl selenate, [K(C12H 24O6)(H2O)][(UO2)(SeO 4)(NO3)] (I), has been prepared by a room-temperature evaporation from the aqueous solutions of uranyl nitrate, selenic acid, potassium nitrate and 18-crown-6 ether. The crystal structure of I [monoclinic, P21/c, a = 7.2404(2), b = 21.2024(7), c = 15.7322(5) Å, β = 91.5810(10)°, V = 2414.19(13) Å3, Z = 4, R1 = 0.023] is based upon the [(UO2)(SeO4)(NO 3)]- one-dimensional uranyl nitrate-selenate chains consisting of UO7 pentagonal bipyramids, SeO4 tetrahedra and nitrate groups. The chains are linked to the [K(18-crown-6)(H 2O)]+ complexes via the K+O bonds to form a "multi-axis transporter" {[K(18-crown-6)(H2O)][(UO 2)(SeO4)(NO3)]} bands that are linked together via weak hydrogen bonds only. The infrared spectroscopy data support the structural data. © 2014 Elsevier B.V.

U2 - 10.1016/j.inoche.2014.04.012

DO - 10.1016/j.inoche.2014.04.012

M3 - Article

VL - 45

SP - 93

EP - 96

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 7003713