TY - JOUR

T1 - NONEQUILIBRIUM THERMODYNAMICS OF THE DYNAMIC SURFACE TENSION.

AU - Kochurova, N. N.

AU - Rusanov, A. I.

PY - 1984

Y1 - 1984

N2 - The process of the relaxation of a surface layer of a multicomponent liquid system consisting of polar and nonpolar molecules and ions has been analyzed by the methods of nonequilibrium thermodynamics. The cases of slow orientation of the molecules on the surface under the conditions of diffusional equilibrium, a diffusion-controlled orientation process on the surface, and an ionic mechanism for the formation of a surface electrical potential have been considered separately. The influence of such a potential on the surface tension of a liquid during relaxation is discussed.

AB - The process of the relaxation of a surface layer of a multicomponent liquid system consisting of polar and nonpolar molecules and ions has been analyzed by the methods of nonequilibrium thermodynamics. The cases of slow orientation of the molecules on the surface under the conditions of diffusional equilibrium, a diffusion-controlled orientation process on the surface, and an ionic mechanism for the formation of a surface electrical potential have been considered separately. The influence of such a potential on the surface tension of a liquid during relaxation is discussed.

UR - http://www.scopus.com/inward/record.url?scp=0021313851&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0021313851

VL - 46

SP - 6

EP - 10

JO - Colloid Journal

JF - Colloid Journal

SN - 1061-933X

IS - 1

ER -