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N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate. / Potapenkov, Vasiliy V.; Levin, Oleg V.; Lukyanov, Daniil A.

в: MolBank, Том 2023, № 2, M1643, 13.05.2023.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{c255be997afe4304a47b3faf0eab7c58,
title = "N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate",
abstract = "Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the 1H and 13C, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).",
author = "Potapenkov, {Vasiliy V.} and Levin, {Oleg V.} and Lukyanov, {Daniil A.}",
year = "2023",
month = may,
day = "13",
doi = "10.3390/m1643",
language = "English",
volume = "2023",
journal = "MolBank",
issn = "1422-8599",
publisher = "MDPI AG",
number = "2",

}

RIS

TY - JOUR

T1 - N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate

AU - Potapenkov, Vasiliy V.

AU - Levin, Oleg V.

AU - Lukyanov, Daniil A.

PY - 2023/5/13

Y1 - 2023/5/13

N2 - Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the 1H and 13C, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).

AB - Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the 1H and 13C, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).

UR - https://www.mendeley.com/catalogue/746f6aee-2892-361d-8217-b372d00e3b7d/

U2 - 10.3390/m1643

DO - 10.3390/m1643

M3 - Article

VL - 2023

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 2

M1 - M1643

ER -

ID: 107414928