Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate. / Potapenkov, Vasiliy V.; Levin, Oleg V.; Lukyanov, Daniil A.
в: MolBank, Том 2023, № 2, M1643, 13.05.2023.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate
AU - Potapenkov, Vasiliy V.
AU - Levin, Oleg V.
AU - Lukyanov, Daniil A.
PY - 2023/5/13
Y1 - 2023/5/13
N2 - Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the 1H and 13C, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).
AB - Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the 1H and 13C, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).
UR - https://www.mendeley.com/catalogue/746f6aee-2892-361d-8217-b372d00e3b7d/
U2 - 10.3390/m1643
DO - 10.3390/m1643
M3 - Article
VL - 2023
JO - MolBank
JF - MolBank
SN - 1422-8599
IS - 2
M1 - M1643
ER -
ID: 107414928