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NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10. / Shelyapina, Marina G.; Silyukov, Oleg I.; Lushpinskaia, Irina P. ; Kurnosenko, Sergey A. ; Mazur, Anton S. ; Shenderovich, I.G.; Zvereva, Irina A.

в: Molecules, Том 25, № 22, 5229, 10.11.2020.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Shelyapina, MG, Silyukov, OI, Lushpinskaia, IP, Kurnosenko, SA, Mazur, AS, Shenderovich, IG & Zvereva, IA 2020, 'NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10', Molecules, Том. 25, № 22, 5229.

APA

Shelyapina, M. G., Silyukov, O. I., Lushpinskaia, I. P., Kurnosenko, S. A., Mazur, A. S., Shenderovich, I. G., & Zvereva, I. A. (2020). NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10. Molecules, 25(22), [5229].

Vancouver

Shelyapina MG, Silyukov OI, Lushpinskaia IP, Kurnosenko SA, Mazur AS, Shenderovich IG и пр. NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10. Molecules. 2020 Нояб. 10;25(22). 5229.

Author

Shelyapina, Marina G. ; Silyukov, Oleg I. ; Lushpinskaia, Irina P. ; Kurnosenko, Sergey A. ; Mazur, Anton S. ; Shenderovich, I.G. ; Zvereva, Irina A. / NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10. в: Molecules. 2020 ; Том 25, № 22.

BibTeX

@article{7160746efedc43f7a0babeb1e66682ca,
title = "NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10",
abstract = "The protonated perovskite-like titanate H2La2Ti3O10 has been used to produce organic-inorganic hybrids with simple organic molecules: methylamine, methanol, monoethanolamine, and n-butylamine. The optimal pathways for the preparation of such hybrids are summarized. Solid-state NMR, combined with thermal analysis, Raman, and IR spectroscopy, has been applied to determine the bonding type in the obtained organic-inorganic hybrids. It has been found that, in the methanolic hybrid, the organic residues are covalently bound to the inorganic matrix. In contrast, in the methylamine and n-butylamine hybrids, the organic molecules are intercalated into the inorganic matrix in cationic forms. The structure of the monoethanolamine hybrid is composite and includes both the covalently bound and intercalated organic species.",
keywords = "layered perovskite-like oxides, organic-inorganic hybrid, intercalation, grafting, NMR",
author = "Shelyapina, {Marina G.} and Silyukov, {Oleg I.} and Lushpinskaia, {Irina P.} and Kurnosenko, {Sergey A.} and Mazur, {Anton S.} and I.G. Shenderovich and Zvereva, {Irina A.}",
note = "Shelyapina, M.G.; Silyukov, O.I.; Lushpinskaia, I.P.; Kurnosenko, S.A.; Mazur, A.S.; Shenderovich, I.G.; Zvereva, I.A. NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10. Molecules 2020, 25, 5229.",
year = "2020",
month = nov,
day = "10",
language = "English",
volume = "25",
journal = "Molecules",
issn = "1420-3049",
publisher = "MDPI AG",
number = "22",

}

RIS

TY - JOUR

T1 - NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10

AU - Shelyapina, Marina G.

AU - Silyukov, Oleg I.

AU - Lushpinskaia, Irina P.

AU - Kurnosenko, Sergey A.

AU - Mazur, Anton S.

AU - Shenderovich, I.G.

AU - Zvereva, Irina A.

N1 - Shelyapina, M.G.; Silyukov, O.I.; Lushpinskaia, I.P.; Kurnosenko, S.A.; Mazur, A.S.; Shenderovich, I.G.; Zvereva, I.A. NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10. Molecules 2020, 25, 5229.

PY - 2020/11/10

Y1 - 2020/11/10

N2 - The protonated perovskite-like titanate H2La2Ti3O10 has been used to produce organic-inorganic hybrids with simple organic molecules: methylamine, methanol, monoethanolamine, and n-butylamine. The optimal pathways for the preparation of such hybrids are summarized. Solid-state NMR, combined with thermal analysis, Raman, and IR spectroscopy, has been applied to determine the bonding type in the obtained organic-inorganic hybrids. It has been found that, in the methanolic hybrid, the organic residues are covalently bound to the inorganic matrix. In contrast, in the methylamine and n-butylamine hybrids, the organic molecules are intercalated into the inorganic matrix in cationic forms. The structure of the monoethanolamine hybrid is composite and includes both the covalently bound and intercalated organic species.

AB - The protonated perovskite-like titanate H2La2Ti3O10 has been used to produce organic-inorganic hybrids with simple organic molecules: methylamine, methanol, monoethanolamine, and n-butylamine. The optimal pathways for the preparation of such hybrids are summarized. Solid-state NMR, combined with thermal analysis, Raman, and IR spectroscopy, has been applied to determine the bonding type in the obtained organic-inorganic hybrids. It has been found that, in the methanolic hybrid, the organic residues are covalently bound to the inorganic matrix. In contrast, in the methylamine and n-butylamine hybrids, the organic molecules are intercalated into the inorganic matrix in cationic forms. The structure of the monoethanolamine hybrid is composite and includes both the covalently bound and intercalated organic species.

KW - layered perovskite-like oxides

KW - organic-inorganic hybrid

KW - intercalation

KW - grafting

KW - NMR

UR - https://www.mdpi.com/1420-3049/25/22/5229

M3 - Article

VL - 25

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 22

M1 - 5229

ER -

ID: 70819469