Standard

NMR and XAS study on doped LaF3. / Denecke, M. A.; Gunßer, W.; Privalov, A. V.; Murin, I. V.

в: Solid State Ionics, Том 52, № 4, 06.1992, стр. 327-331.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Denecke, MA, Gunßer, W, Privalov, AV & Murin, IV 1992, 'NMR and XAS study on doped LaF3', Solid State Ionics, Том. 52, № 4, стр. 327-331. https://doi.org/10.1016/0167-2738(92)90179-S

APA

Denecke, M. A., Gunßer, W., Privalov, A. V., & Murin, I. V. (1992). NMR and XAS study on doped LaF3. Solid State Ionics, 52(4), 327-331. https://doi.org/10.1016/0167-2738(92)90179-S

Vancouver

Denecke MA, Gunßer W, Privalov AV, Murin IV. NMR and XAS study on doped LaF3. Solid State Ionics. 1992 Июнь;52(4):327-331. https://doi.org/10.1016/0167-2738(92)90179-S

Author

Denecke, M. A. ; Gunßer, W. ; Privalov, A. V. ; Murin, I. V. / NMR and XAS study on doped LaF3. в: Solid State Ionics. 1992 ; Том 52, № 4. стр. 327-331.

BibTeX

@article{3f099bda032b40e9bba5b6762485cc81,
title = "NMR and XAS study on doped LaF3",
abstract = "Temperature dependent NMR measurements as well as XAS investigations on La1-xSrxF3-x (x=0.0, 0.01, 0.05, 0.16) have been performed to study the fluorine diffusion in these solid electrolytes and to elucidate the effect that doping with heterovalent SrF2 has on LaF3. A three-stage process of diffusion was observed. Upon increasing temperature, initial ionic exchange begins in the F1 sublattice. At even higher temperatures, dependent upon dopant concentration, ionic exchange between the F1 and F2,3 sublattices takes place. A further increase in temperature eventually leads to exchange over all F- structural positions.",
author = "Denecke, {M. A.} and W. Gun{\ss}er and Privalov, {A. V.} and Murin, {I. V.}",
note = "Funding Information: We wish to thank the Bundesminister f'tir For-schung und Technik for financial support. The project number is GU2HAM-O.",
year = "1992",
month = jun,
doi = "10.1016/0167-2738(92)90179-S",
language = "English",
volume = "52",
pages = "327--331",
journal = "Solid State Ionics",
issn = "0167-2738",
publisher = "Elsevier",
number = "4",

}

RIS

TY - JOUR

T1 - NMR and XAS study on doped LaF3

AU - Denecke, M. A.

AU - Gunßer, W.

AU - Privalov, A. V.

AU - Murin, I. V.

N1 - Funding Information: We wish to thank the Bundesminister f'tir For-schung und Technik for financial support. The project number is GU2HAM-O.

PY - 1992/6

Y1 - 1992/6

N2 - Temperature dependent NMR measurements as well as XAS investigations on La1-xSrxF3-x (x=0.0, 0.01, 0.05, 0.16) have been performed to study the fluorine diffusion in these solid electrolytes and to elucidate the effect that doping with heterovalent SrF2 has on LaF3. A three-stage process of diffusion was observed. Upon increasing temperature, initial ionic exchange begins in the F1 sublattice. At even higher temperatures, dependent upon dopant concentration, ionic exchange between the F1 and F2,3 sublattices takes place. A further increase in temperature eventually leads to exchange over all F- structural positions.

AB - Temperature dependent NMR measurements as well as XAS investigations on La1-xSrxF3-x (x=0.0, 0.01, 0.05, 0.16) have been performed to study the fluorine diffusion in these solid electrolytes and to elucidate the effect that doping with heterovalent SrF2 has on LaF3. A three-stage process of diffusion was observed. Upon increasing temperature, initial ionic exchange begins in the F1 sublattice. At even higher temperatures, dependent upon dopant concentration, ionic exchange between the F1 and F2,3 sublattices takes place. A further increase in temperature eventually leads to exchange over all F- structural positions.

UR - http://www.scopus.com/inward/record.url?scp=0026881268&partnerID=8YFLogxK

U2 - 10.1016/0167-2738(92)90179-S

DO - 10.1016/0167-2738(92)90179-S

M3 - Article

AN - SCOPUS:0026881268

VL - 52

SP - 327

EP - 331

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - 4

ER -

ID: 88000963