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Nickel salicylideniminato 1D MOFs via electrochemical polymerization. / Lukyanov, Daniil A.; Vereshchagin, Anatoliy A.; Beletskii, Evgenii V.; Atangulov, Arslan B.; Yankin, Andrei N.; Sizov, Vladimir V.; Levin, Oleg Vladislavovich.

в: ChemElectroChem, 15.11.2021.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{207f7edc29a447e48bcf8bbb53645089,
title = "Nickel salicylideniminato 1D MOFs via electrochemical polymerization",
abstract = "Polymers derived from nickel complexes of salicylaldimines are extensively studied due to their electrochemical, catalytic and sensing properties. However, almost all studies are devoted to the polymers obtained from tetradentate bis(salicylidenaldiminato) complexes, in which the aromatic rings are bound via an imine bridge. Herein we report a first systematic study focused on the polymerization of salicylaldimine nickel complexes without a bridge between the imine fragments. As a result, an impact of the ligand structure on the polymerization ability of the complexes and electrochemical behavior of the polymers obtained thereof was discovered and quantified. An observed phenomenon was rationalized both computationally and experimentally, involving the electrochemical and spectroelectrochemical techniques.",
keywords = "nickel salicylaldimine complexes, DFT calculations, conductivity measurement, structure / properties dependence",
author = "Lukyanov, {Daniil A.} and Vereshchagin, {Anatoliy A.} and Beletskii, {Evgenii V.} and Atangulov, {Arslan B.} and Yankin, {Andrei N.} and Sizov, {Vladimir V.} and Levin, {Oleg Vladislavovich}",
note = "https://doi.org/10.1002/celc.202101316",
year = "2021",
month = nov,
day = "15",
doi = "10.1002/celc.202101316",
language = "русский",
journal = "ChemElectroChem",
issn = "2196-0216",
publisher = "Wiley-Blackwell",

}

RIS

TY - JOUR

T1 - Nickel salicylideniminato 1D MOFs via electrochemical polymerization

AU - Lukyanov, Daniil A.

AU - Vereshchagin, Anatoliy A.

AU - Beletskii, Evgenii V.

AU - Atangulov, Arslan B.

AU - Yankin, Andrei N.

AU - Sizov, Vladimir V.

AU - Levin, Oleg Vladislavovich

N1 - https://doi.org/10.1002/celc.202101316

PY - 2021/11/15

Y1 - 2021/11/15

N2 - Polymers derived from nickel complexes of salicylaldimines are extensively studied due to their electrochemical, catalytic and sensing properties. However, almost all studies are devoted to the polymers obtained from tetradentate bis(salicylidenaldiminato) complexes, in which the aromatic rings are bound via an imine bridge. Herein we report a first systematic study focused on the polymerization of salicylaldimine nickel complexes without a bridge between the imine fragments. As a result, an impact of the ligand structure on the polymerization ability of the complexes and electrochemical behavior of the polymers obtained thereof was discovered and quantified. An observed phenomenon was rationalized both computationally and experimentally, involving the electrochemical and spectroelectrochemical techniques.

AB - Polymers derived from nickel complexes of salicylaldimines are extensively studied due to their electrochemical, catalytic and sensing properties. However, almost all studies are devoted to the polymers obtained from tetradentate bis(salicylidenaldiminato) complexes, in which the aromatic rings are bound via an imine bridge. Herein we report a first systematic study focused on the polymerization of salicylaldimine nickel complexes without a bridge between the imine fragments. As a result, an impact of the ligand structure on the polymerization ability of the complexes and electrochemical behavior of the polymers obtained thereof was discovered and quantified. An observed phenomenon was rationalized both computationally and experimentally, involving the electrochemical and spectroelectrochemical techniques.

KW - nickel salicylaldimine complexes

KW - DFT calculations

KW - conductivity measurement

KW - structure / properties dependence

UR - https://www.mendeley.com/catalogue/7497482c-d0cc-37be-81ee-81ee8bb58500/

U2 - 10.1002/celc.202101316

DO - 10.1002/celc.202101316

M3 - статья

JO - ChemElectroChem

JF - ChemElectroChem

SN - 2196-0216

ER -

ID: 88339394