Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
New theory of equation of state for surface monolayer. / Rusanov, Anatoly I.
в: Journal of Chemical Physics, Том 120, № 22, 08.06.2004, стр. 10736-10747.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - New theory of equation of state for surface monolayer
AU - Rusanov, Anatoly I.
PY - 2004/6/8
Y1 - 2004/6/8
N2 - A statistical-thermodynamic approach to derive an equation of state for a surface monolayer was analyzed on the basis of excluded area. The equations of state for a surface monolayer were generated by deriving a master differential equation relating surface pressure to excluded area. It was shown that the crudest solution of the master equation reproduces the known van Laar and Frumkin equations of state. For monolayers containing anisometric particles, an orientation equation of state was proposed.
AB - A statistical-thermodynamic approach to derive an equation of state for a surface monolayer was analyzed on the basis of excluded area. The equations of state for a surface monolayer were generated by deriving a master differential equation relating surface pressure to excluded area. It was shown that the crudest solution of the master equation reproduces the known van Laar and Frumkin equations of state. For monolayers containing anisometric particles, an orientation equation of state was proposed.
UR - http://www.scopus.com/inward/record.url?scp=2942685607&partnerID=8YFLogxK
U2 - 10.1063/1.1737301
DO - 10.1063/1.1737301
M3 - Article
AN - SCOPUS:2942685607
VL - 120
SP - 10736
EP - 10747
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 22
ER -
ID: 95701180