[Figure not available: see fulltext.] A sequence of microwave-assisted Suzuki cross-coupling reaction and bromination with N-bromosuccinimide was used for the synthesis of 3,3'-(5,5'-{5-[5-(9-ethyl-9H-carbazol-3-yl)-3-hexylthiophen-2-yl]pyrimidine-4,6-diyl}bis(thiophene-5,2-diyl))bis(9-ethyl-9H-carbazole). The obtained compound was characterized with regard to its optical properties, as well as possible applications in sensors for nitroaromatic compounds in acetonitrile solutions and in vapor phase.