Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table

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Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table. / Davidian, A.G.; Kudrev, A.G.; Myund, L.A.; Khripun, M.K.

в: Journal of Near Infrared Spectroscopy, Том 22, № 1, 2014, стр. 27-34.

Результаты исследований: Научные публикации в периодических изданиях › статья

BibTeX

@article{8c0ff26b2e834022b1bb5aad12676ab9,

title = "Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table",

abstract = "Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. {\textcopyright} IM Publications LLP 2014.",

author = "A.G. Davidian and A.G. Kudrev and L.A. Myund and M.K. Khripun",

year = "2014",

doi = "10.1255/jnirs.1090",

language = "English",

volume = "22",

pages = "27--34",

journal = "Journal of Near Infrared Spectroscopy",

issn = "0967-0335",

publisher = "I M Publications",

number = "1",

}

RIS

TY - JOUR

T1 - Near infrared spectral studies of aqueous solutions of metal perchlorates in groups I A, II A, II B, III A and III B of the Periodic Table

AU - Davidian, A.G.

AU - Kudrev, A.G.

AU - Myund, L.A.

AU - Khripun, M.K.

PY - 2014

Y1 - 2014

N2 - Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. © IM Publications LLP 2014.

AB - Chemometrics of NIR spectra of aqueous salt solutions M(ClO4)n, where Mn+: Li+, Na+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Cd2+, Al3+, Ga3+, In3+, Sc3+, Y3+, La3+ were used to establish the effect of the cation nature on the structure of aqueous electrolytes solutions. Principal component analysis showed that near infrared (NIR) spectra of the systems under study are grouped into clusters. It was found that the values of the eutectic concentrations of aqueous salt solutions and the polarising powers of cations correlate. The combined use of NIR spectroscopy, chemometrics of the spectral data and a generalised phenomenological model of the structure of aqueous electrolytes solutions is a new approach to studying of the structure of concentrated solutions. © IM Publications LLP 2014.

U2 - 10.1255/jnirs.1090

DO - 10.1255/jnirs.1090

M3 - Article

VL - 22

SP - 27

EP - 34

JO - Journal of Near Infrared Spectroscopy

JF - Journal of Near Infrared Spectroscopy

SN - 0967-0335

IS - 1

ER -

ID: 5706700