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N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. / Nelyubin, A. V.; Selivanov, N. A.; Bykov, A. Yu; Klyukin, I. N.; Novikov, A. S.; Zhdanov, A. P.; Zhizhin, K. Yu; Kuznetsov, N. T.

в: Russian Journal of Inorganic Chemistry, Том 65, № 6, 01.06.2020, стр. 795-799.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Nelyubin, AV, Selivanov, NA, Bykov, AY, Klyukin, IN, Novikov, AS, Zhdanov, AP, Zhizhin, KY & Kuznetsov, NT 2020, 'N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion', Russian Journal of Inorganic Chemistry, Том. 65, № 6, стр. 795-799. https://doi.org/10.1134/S0036023620060133

APA

Nelyubin, A. V., Selivanov, N. A., Bykov, A. Y., Klyukin, I. N., Novikov, A. S., Zhdanov, A. P., Zhizhin, K. Y., & Kuznetsov, N. T. (2020). N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. Russian Journal of Inorganic Chemistry, 65(6), 795-799. https://doi.org/10.1134/S0036023620060133

Vancouver

Nelyubin AV, Selivanov NA, Bykov AY, Klyukin IN, Novikov AS, Zhdanov AP и пр. N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. Russian Journal of Inorganic Chemistry. 2020 Июнь 1;65(6):795-799. https://doi.org/10.1134/S0036023620060133

Author

Nelyubin, A. V. ; Selivanov, N. A. ; Bykov, A. Yu ; Klyukin, I. N. ; Novikov, A. S. ; Zhdanov, A. P. ; Zhizhin, K. Yu ; Kuznetsov, N. T. / N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. в: Russian Journal of Inorganic Chemistry. 2020 ; Том 65, № 6. стр. 795-799.

BibTeX

@article{9245ac6ae40c42bc9a0f1a0e86862766,
title = "N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion",
abstract = "Abstract: Methods for the preparation of N-substituted hydroxylamine [B12H11NH2OH]– have been developed and optimized. The possibility of using two synthetic methods has been shown: (i) based on the hydroxylation of the deprotonated amino-closo-dodecaborate and (ii) the ipso-substitution of the iodonium substituent with free hydroxylamine. A theoretical study of the [B12H11NH2OH]– anion has been carried out by quantum-chemical calculations in the framework of density functional theory in order to determine its main structural characteristics.",
keywords = "boron cluster anions, closo-dodecaborates, nucleophilic substitution, CLOSO-DECABORATE ANION, ALBUMINS, NUCLEOPHILIC-ADDITION",
author = "Nelyubin, {A. V.} and Selivanov, {N. A.} and Bykov, {A. Yu} and Klyukin, {I. N.} and Novikov, {A. S.} and Zhdanov, {A. P.} and Zhizhin, {K. Yu} and Kuznetsov, {N. T.}",
note = "Nelyubin, A.V., Selivanov, N.A., Bykov, A.Y. et al. N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. Russ. J. Inorg. Chem. 65, 795–799 (2020). https://doi.org/10.1134/S0036023620060133",
year = "2020",
month = jun,
day = "1",
doi = "10.1134/S0036023620060133",
language = "English",
volume = "65",
pages = "795--799",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion

AU - Nelyubin, A. V.

AU - Selivanov, N. A.

AU - Bykov, A. Yu

AU - Klyukin, I. N.

AU - Novikov, A. S.

AU - Zhdanov, A. P.

AU - Zhizhin, K. Yu

AU - Kuznetsov, N. T.

N1 - Nelyubin, A.V., Selivanov, N.A., Bykov, A.Y. et al. N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. Russ. J. Inorg. Chem. 65, 795–799 (2020). https://doi.org/10.1134/S0036023620060133

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Abstract: Methods for the preparation of N-substituted hydroxylamine [B12H11NH2OH]– have been developed and optimized. The possibility of using two synthetic methods has been shown: (i) based on the hydroxylation of the deprotonated amino-closo-dodecaborate and (ii) the ipso-substitution of the iodonium substituent with free hydroxylamine. A theoretical study of the [B12H11NH2OH]– anion has been carried out by quantum-chemical calculations in the framework of density functional theory in order to determine its main structural characteristics.

AB - Abstract: Methods for the preparation of N-substituted hydroxylamine [B12H11NH2OH]– have been developed and optimized. The possibility of using two synthetic methods has been shown: (i) based on the hydroxylation of the deprotonated amino-closo-dodecaborate and (ii) the ipso-substitution of the iodonium substituent with free hydroxylamine. A theoretical study of the [B12H11NH2OH]– anion has been carried out by quantum-chemical calculations in the framework of density functional theory in order to determine its main structural characteristics.

KW - boron cluster anions

KW - closo-dodecaborates

KW - nucleophilic substitution

KW - CLOSO-DECABORATE ANION

KW - ALBUMINS

KW - NUCLEOPHILIC-ADDITION

UR - http://www.scopus.com/inward/record.url?scp=85087281933&partnerID=8YFLogxK

U2 - 10.1134/S0036023620060133

DO - 10.1134/S0036023620060133

M3 - Article

AN - SCOPUS:85087281933

VL - 65

SP - 795

EP - 799

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 6

ER -

ID: 62026171