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Nanothermodynamics. / Rusanov, A. I.
в: Russian Journal of Physical Chemistry A, Том 77, № 10, 10.2003, стр. 1558-1563.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Nanothermodynamics
AU - Rusanov, A. I.
PY - 2003/10
Y1 - 2003/10
N2 - Generally, nanothermodynamics differs from the thermodynamics of small systems by the need to taking into account the size dependence of the surface tension of a nanoparticle. Attention is also given to the development of Gibbs' thermodynamics, namely, a more rigorous definition of the separating surface and a more general mechanical equilibrium condition are given. The dependence of the chemical potential of a substance in the bulk and surface layer of a nanoparticle the size of what - the nanoparticle or the substance is analyzed with emphasis on the surface tension effect. Stable and unstable equilibrium states during microphase growth are revealed.
AB - Generally, nanothermodynamics differs from the thermodynamics of small systems by the need to taking into account the size dependence of the surface tension of a nanoparticle. Attention is also given to the development of Gibbs' thermodynamics, namely, a more rigorous definition of the separating surface and a more general mechanical equilibrium condition are given. The dependence of the chemical potential of a substance in the bulk and surface layer of a nanoparticle the size of what - the nanoparticle or the substance is analyzed with emphasis on the surface tension effect. Stable and unstable equilibrium states during microphase growth are revealed.
UR - http://www.scopus.com/inward/record.url?scp=0242690177&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0242690177
VL - 77
SP - 1558
EP - 1563
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 10
ER -
ID: 95716684