DOI

  • Ting Lei
  • Nan Ma
  • Juan Hong
  • Thomas Tuch
  • Xin Wang
  • Zhibin Wang
  • Mira Pöhlker
  • Maofa Ge
  • Weigang Wang
  • Eugene Mikhailov
  • Thorsten Hoffmann
  • Ulrich Pöschl
  • Hang Su
  • Alfred Wiedensohler
  • Yafang Cheng

Interactions between water and nanoparticles are relevant for atmospheric multiphase processes, physical chemistry, and materials science. Current knowledge of the hygroscopic and related physicochemical properties of nanoparticles, however, is restricted by the limitations of the available measurement techniques. Here, we present the design and performance of a nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) apparatus that enables high accuracy and precision in hygroscopic growth measurements of aerosol nanoparticles with diameters less than 10 nm. Detailed methods of calibration and validation are provided. Besides maintaining accurate and stable sheath and aerosol flow rates (1 %), high accuracy of the differential mobility analyzer (DMA) voltage (0:1 %) in the range of 0-50V is crucial for achieving accurate sizing and small sizing offsets between the two DMAs (1:4 %). To maintain a stable relative humidity (RH), the humidification system and the second DMA are placed in a well-insulated and air conditioner housing (0:1 K). We also tested and discussed different ways of preventing predeliquescence in the second DMA. Our measurement results for ammonium sulfate nanoparticles are in good agreement with Biskos et al. (2006b), with no significant size effect on the deliquescence and efflorescence relative humidity (DRH and ERH, respectively) at diameters down to 6 nm. For sodium sulfate nanoparticles, however, we find a pronounced size dependence of DRH and ERH between 20 and 6 nm nanoparticles.

Язык оригиналаАнглийский
Страницы (с-по)5551-5567
Число страниц17
ЖурналAtmospheric Measurement Techniques
Том13
Номер выпуска10
DOI
СостояниеОпубликовано - 20 окт 2020

    Предметные области Scopus

  • Наука об атмосфере

    Области исследований

  • анализатор гигроскопических свойств аэрозолей 10 нм аэрозолей

ID: 71961547