Standard

Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3. / Markovski, Mishel R. ; Siidra, Oleg I.; Charkin, Dmitri O. ; Nazarchuk, Evgeny V. ; Grishaev, Vasili Yu. .

в: Zeitschrift fur Kristallographie - Crystalline Materials, 2020.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Markovski, MR, Siidra, OI, Charkin, DO, Nazarchuk, EV & Grishaev, VY 2020, 'Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3', Zeitschrift fur Kristallographie - Crystalline Materials.

APA

Markovski, M. R., Siidra, O. I., Charkin, D. O., Nazarchuk, E. V., & Grishaev, V. Y. (2020). Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3. Zeitschrift fur Kristallographie - Crystalline Materials, [1-5].

Vancouver

Markovski MR, Siidra OI, Charkin DO, Nazarchuk EV, Grishaev VY. Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3. Zeitschrift fur Kristallographie - Crystalline Materials. 2020. 1-5.

Author

Markovski, Mishel R. ; Siidra, Oleg I. ; Charkin, Dmitri O. ; Nazarchuk, Evgeny V. ; Grishaev, Vasili Yu. . / Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3. в: Zeitschrift fur Kristallographie - Crystalline Materials. 2020.

BibTeX

@article{2ab379864df249449c3c9c773ddabea9,
title = "Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3",
abstract = "KCl72H 2SeO 3 and CsCl7H 2SeO 3 have been synthesized using solution evaporation methods from aqueous solution. Both compounds are monoclinic ( P2/ n and P2 1/ c) and demonstrate new structure types. One symmetrically unique SeO(OH) 2 molecule is present in each structure. SeO(OH) 2 molecules via strong hydrogen bonds form chains in KCl72H 2SeO 3 and layers in ?sCl7H 2SeO 3. The structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3 can be described as consisting of ionic KCl chains and CsCl layers incorporated into the covalent- and hydrogen-bonded H 2SeO 3 matrix. To the best of our knowledge, the cases when selenious acid acts as a contributor to the molecular building blocks of salt-inclusion structures are not known to date.",
keywords = "HALIDES, molecular inorganic polymers, selenious acid, Selenite",
author = "Markovski, {Mishel R.} and Siidra, {Oleg I.} and Charkin, {Dmitri O.} and Nazarchuk, {Evgeny V.} and Grishaev, {Vasili Yu.}",
year = "2020",
language = "English",
journal = "Zeitschrift fur Kristallographie - Crystalline Materials",
issn = "2194-4946",
publisher = "De Gruyter",

}

RIS

TY - JOUR

T1 - Molecular inorganic polymers: synthesis and crystal structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3

AU - Markovski, Mishel R.

AU - Siidra, Oleg I.

AU - Charkin, Dmitri O.

AU - Nazarchuk, Evgeny V.

AU - Grishaev, Vasili Yu.

PY - 2020

Y1 - 2020

N2 - KCl72H 2SeO 3 and CsCl7H 2SeO 3 have been synthesized using solution evaporation methods from aqueous solution. Both compounds are monoclinic ( P2/ n and P2 1/ c) and demonstrate new structure types. One symmetrically unique SeO(OH) 2 molecule is present in each structure. SeO(OH) 2 molecules via strong hydrogen bonds form chains in KCl72H 2SeO 3 and layers in ?sCl7H 2SeO 3. The structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3 can be described as consisting of ionic KCl chains and CsCl layers incorporated into the covalent- and hydrogen-bonded H 2SeO 3 matrix. To the best of our knowledge, the cases when selenious acid acts as a contributor to the molecular building blocks of salt-inclusion structures are not known to date.

AB - KCl72H 2SeO 3 and CsCl7H 2SeO 3 have been synthesized using solution evaporation methods from aqueous solution. Both compounds are monoclinic ( P2/ n and P2 1/ c) and demonstrate new structure types. One symmetrically unique SeO(OH) 2 molecule is present in each structure. SeO(OH) 2 molecules via strong hydrogen bonds form chains in KCl72H 2SeO 3 and layers in ?sCl7H 2SeO 3. The structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3 can be described as consisting of ionic KCl chains and CsCl layers incorporated into the covalent- and hydrogen-bonded H 2SeO 3 matrix. To the best of our knowledge, the cases when selenious acid acts as a contributor to the molecular building blocks of salt-inclusion structures are not known to date.

KW - HALIDES

KW - molecular inorganic polymers

KW - selenious acid

KW - Selenite

UR - https://www.degruyter.com/view/journals/zkri/ahead-of-print/article-10.1515-zkri-2020-0062/article-10.1515-zkri-2020-0062.xml

M3 - Article

JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

SN - 2194-4946

M1 - 1-5

ER -

ID: 64694562