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Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors. / Давыдова, Елена Иоановна; Спиридонова, Дарья Валерьевна; Корняков, Илья Викторович; Крюкова, Мария Александровна; Помогаева, Анна Владимировна; Тимошкин, Алексей Юрьевич.

в: Zeitschrift fur Anorganische und Allgemeine Chemie, 03.12.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Давыдова, ЕИ, Спиридонова, ДВ, Корняков, ИВ, Крюкова, МА, Помогаева, АВ & Тимошкин, АЮ 2025, 'Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors', Zeitschrift fur Anorganische und Allgemeine Chemie. https://doi.org/10.1002/zaac.202500185

APA

Давыдова, Е. И., Спиридонова, Д. В., Корняков, И. В., Крюкова, М. А., Помогаева, А. В., & Тимошкин, А. Ю. (2025). Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors. Zeitschrift fur Anorganische und Allgemeine Chemie. https://doi.org/10.1002/zaac.202500185

Vancouver

Давыдова ЕИ, Спиридонова ДВ, Корняков ИВ, Крюкова МА, Помогаева АВ, Тимошкин АЮ. Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors. Zeitschrift fur Anorganische und Allgemeine Chemie. 2025 Дек. 3. https://doi.org/10.1002/zaac.202500185

Author

Давыдова, Елена Иоановна ; Спиридонова, Дарья Валерьевна ; Корняков, Илья Викторович ; Крюкова, Мария Александровна ; Помогаева, Анна Владимировна ; Тимошкин, Алексей Юрьевич. / Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors. в: Zeitschrift fur Anorganische und Allgemeine Chemie. 2025.

BibTeX

@article{50b6036bc7034eeebc6e49cb89ea2f60,
title = "Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors",
abstract = "Results of the joint experimental and computational studies of structural features, bonding, and thermodynamic properties of molecular complexes of iodine monobromide with bidentate nonchelating N-containing donors, pyrazine (pyz), 4,4′-bipyridine (bipy), and 1,2-bis(4-pyridyl)ethane (bpa) are reported. Comparison of structural, energetic, and electronic properties reveals that the Lewis basicity with respect to IBr increases in the order pyz < bipy < bpa, while Lewis acidity with respect to pyz increases in the order I2< IBr < ICl. Stabilization of IBr by complexation with bidentate nonchelating Lewis bases allows to recommend (IBr)2·L complexes as a convenient source of IBr.",
keywords = "2-bis(4-pyridyl)ethane, 4,4′-bipyridine, iodine monobromide complexes, pyrazine, structures",
author = "Давыдова, {Елена Иоановна} and Спиридонова, {Дарья Валерьевна} and Корняков, {Илья Викторович} and Крюкова, {Мария Александровна} and Помогаева, {Анна Владимировна} and Тимошкин, {Алексей Юрьевич}",
year = "2025",
month = dec,
day = "3",
doi = "10.1002/zaac.202500185",
language = "English",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",

}

RIS

TY - JOUR

T1 - Molecular Complexes of Iodine Monobromide with Bifunctional N-containing Donors

AU - Давыдова, Елена Иоановна

AU - Спиридонова, Дарья Валерьевна

AU - Корняков, Илья Викторович

AU - Крюкова, Мария Александровна

AU - Помогаева, Анна Владимировна

AU - Тимошкин, Алексей Юрьевич

PY - 2025/12/3

Y1 - 2025/12/3

N2 - Results of the joint experimental and computational studies of structural features, bonding, and thermodynamic properties of molecular complexes of iodine monobromide with bidentate nonchelating N-containing donors, pyrazine (pyz), 4,4′-bipyridine (bipy), and 1,2-bis(4-pyridyl)ethane (bpa) are reported. Comparison of structural, energetic, and electronic properties reveals that the Lewis basicity with respect to IBr increases in the order pyz < bipy < bpa, while Lewis acidity with respect to pyz increases in the order I2< IBr < ICl. Stabilization of IBr by complexation with bidentate nonchelating Lewis bases allows to recommend (IBr)2·L complexes as a convenient source of IBr.

AB - Results of the joint experimental and computational studies of structural features, bonding, and thermodynamic properties of molecular complexes of iodine monobromide with bidentate nonchelating N-containing donors, pyrazine (pyz), 4,4′-bipyridine (bipy), and 1,2-bis(4-pyridyl)ethane (bpa) are reported. Comparison of structural, energetic, and electronic properties reveals that the Lewis basicity with respect to IBr increases in the order pyz < bipy < bpa, while Lewis acidity with respect to pyz increases in the order I2< IBr < ICl. Stabilization of IBr by complexation with bidentate nonchelating Lewis bases allows to recommend (IBr)2·L complexes as a convenient source of IBr.

KW - 2-bis(4-pyridyl)ethane

KW - 4,4′-bipyridine

KW - iodine monobromide complexes

KW - pyrazine

KW - structures

UR - https://www.mendeley.com/catalogue/260e0fee-20cf-388f-ae2b-1789637f9e96/

U2 - 10.1002/zaac.202500185

DO - 10.1002/zaac.202500185

M3 - Article

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

ER -

ID: 145650285