It is demonstrated experimentally, in a pulsed discharge, that it is possible to modify the "tail" of a nonlocal electron energy distribution (EED) without significantly changing the electron density and temperature (mean energy). The EED tail is modified by changing the potential of a small portion of the plasma boundary and/or by changing the volume creation rate of electrons with energies in the range of the tail of the EED. The discussed effects are a direct result of the nonlocal nature of the EED and have applications to a number of basic research issues associated with discharges under nonequilibrium conditions. As an example, we discuss the possibility of utilizing these methods to measure electron impact excitation cross sections from the metastable states of atoms, which are difficult to measure by other means. The experiments have been conducted in an argon and argon-nitrogen pulsed rf inductively coupled plasma discharge.