The inhomogeneous mechanism of band shape formation is considered for XH vibrational modes of hydrogen bonded complexes (AD-H...B. Experimentally observed bands are shown to result from superposition of separate bands corresponding to hot, with respect to low-frequency intermolecular vibrations, transitions. Spectral band shapes are substantially influenced by Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of diverse spectral manifestations of Fermi resonance are predicted (a hole at the internal mode frequency, the appearance of an intense narrow band, intensity redistribution between separate parts of a contour, etc), and their dependence are examined on magnitudes and signs of matrix elements determining unperturbed band intensities, as well as on the matrix element of an anharmonic part of the Hamiltonian.
Язык оригиналаанглийский
Страницы (с-по)647-654
Число страниц8
ЖурналOptics and Spectroscopy (English translation of Optika i Spektroskopiya)
Том76
Номер выпуска5
СостояниеОпубликовано - 1 мая 1994

ID: 108591998