Mixed-ligand complexes of N-vinylpyrrolidone/N-vinylformamide/N-vinyl iminodiacedic acid copolymers and diethyldithiocarbamate as a co-ligand with indium/indium-111

Standard

Mixed-ligand complexes of N-vinylpyrrolidone/N-vinylformamide/N-vinyl iminodiacedic acid copolymers and diethyldithiocarbamate as a co-ligand with indium/indium-111. / Gorshkov, N. I.; Alekseev, I. E.; Miroslavov, A. E.; Murko, A. Y.; Lumpov, A. A.; Krasikov, V. D.; Suglobov, D. N.

в: International Journal of Polymer Analysis and Characterization, Том 23, № 4, 19.05.2018, стр. 290-299.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Gorshkov, N. I. ; Alekseev, I. E. ; Miroslavov, A. E. ; Murko, A. Y. ; Lumpov, A. A. ; Krasikov, V. D. ; Suglobov, D. N. / Mixed-ligand complexes of N-vinylpyrrolidone/N-vinylformamide/N-vinyl iminodiacedic acid copolymers and diethyldithiocarbamate as a co-ligand with indium/indium-111. в: International Journal of Polymer Analysis and Characterization. 2018 ; Том 23, № 4. стр. 290-299.

BibTeX

@article{c14129280e12412fbc1e9bbe3f943312,

title = "Mixed-ligand complexes of N-vinylpyrrolidone/N-vinylformamide/N-vinyl iminodiacedic acid copolymers and diethyldithiocarbamate as a co-ligand with indium/indium-111",

abstract = "Mixed-ligand metal-polymer complexes (MPC) of N-vinylpyrrolidone-N-vinylformamide-N-vinyl iminodiacedic acid (VP-VFA-VIDA) copolymers and diethyldithiocarbamate (DEDTC) as a co-ligand with indium were synthesized under mild conditions and pH close to physiological values. Isolated MPC were characterized by UV, IR, 1H NMR, atomic absorption spectrophotometry, and HPLC. The obtained data implied that the MPC contain 8–10 wt% of (IDA)In(DEDTC) fragments. The optimal conditions for radiochemical synthesis of VP-VFA-VIDA-111In-(DEDTC) metal-polymer complex with mixed ligands were defined. The closest coordination environment of 111In was studied by perturbed angular correlation technique. The obtained data are in good agreement with the information about weight amounts of the corresponding indium MPC.",

keywords = "Indium-111, mixed-ligand metal-polymer complexes, N-vinylamide copolymers",

author = "Gorshkov, {N. I.} and Alekseev, {I. E.} and Miroslavov, {A. E.} and Murko, {A. Y.} and Lumpov, {A. A.} and Krasikov, {V. D.} and Suglobov, {D. N.}",

year = "2018",

month = may,

day = "19",

doi = "10.1080/1023666X.2017.1421060",

language = "English",

volume = "23",

pages = "290--299",

journal = "International Journal of Polymer Analysis and Characterization",

issn = "1023-666X",

publisher = "Taylor & Francis",

number = "4",

}

RIS

TY - JOUR

T1 - Mixed-ligand complexes of N-vinylpyrrolidone/N-vinylformamide/N-vinyl iminodiacedic acid copolymers and diethyldithiocarbamate as a co-ligand with indium/indium-111

AU - Gorshkov, N. I.

AU - Alekseev, I. E.

AU - Miroslavov, A. E.

AU - Murko, A. Y.

AU - Lumpov, A. A.

AU - Krasikov, V. D.

AU - Suglobov, D. N.

PY - 2018/5/19

Y1 - 2018/5/19

N2 - Mixed-ligand metal-polymer complexes (MPC) of N-vinylpyrrolidone-N-vinylformamide-N-vinyl iminodiacedic acid (VP-VFA-VIDA) copolymers and diethyldithiocarbamate (DEDTC) as a co-ligand with indium were synthesized under mild conditions and pH close to physiological values. Isolated MPC were characterized by UV, IR, 1H NMR, atomic absorption spectrophotometry, and HPLC. The obtained data implied that the MPC contain 8–10 wt% of (IDA)In(DEDTC) fragments. The optimal conditions for radiochemical synthesis of VP-VFA-VIDA-111In-(DEDTC) metal-polymer complex with mixed ligands were defined. The closest coordination environment of 111In was studied by perturbed angular correlation technique. The obtained data are in good agreement with the information about weight amounts of the corresponding indium MPC.

AB - Mixed-ligand metal-polymer complexes (MPC) of N-vinylpyrrolidone-N-vinylformamide-N-vinyl iminodiacedic acid (VP-VFA-VIDA) copolymers and diethyldithiocarbamate (DEDTC) as a co-ligand with indium were synthesized under mild conditions and pH close to physiological values. Isolated MPC were characterized by UV, IR, 1H NMR, atomic absorption spectrophotometry, and HPLC. The obtained data implied that the MPC contain 8–10 wt% of (IDA)In(DEDTC) fragments. The optimal conditions for radiochemical synthesis of VP-VFA-VIDA-111In-(DEDTC) metal-polymer complex with mixed ligands were defined. The closest coordination environment of 111In was studied by perturbed angular correlation technique. The obtained data are in good agreement with the information about weight amounts of the corresponding indium MPC.

KW - Indium-111

KW - mixed-ligand metal-polymer complexes

KW - N-vinylamide copolymers

UR - http://www.scopus.com/inward/record.url?scp=85044738324&partnerID=8YFLogxK

U2 - 10.1080/1023666X.2017.1421060

DO - 10.1080/1023666X.2017.1421060

M3 - Article

AN - SCOPUS:85044738324

VL - 23

SP - 290

EP - 299

JO - International Journal of Polymer Analysis and Characterization

JF - International Journal of Polymer Analysis and Characterization

SN - 1023-666X

IS - 4

ER -

ID: 76834460