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Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data. / Dvinskikh, S. V.; Murin, I. V.; Privalov, A. F.; Pronkin, A. A.; Rössler, E.; Vieth, H. M.

в: Journal of Non-Crystalline Solids, Том 240, № 1-3, 02.10.1998, стр. 79-90.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Dvinskikh, SV, Murin, IV, Privalov, AF, Pronkin, AA, Rössler, E & Vieth, HM 1998, 'Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data', Journal of Non-Crystalline Solids, Том. 240, № 1-3, стр. 79-90. https://doi.org/10.1016/S0022-3093(98)00702-9

APA

Dvinskikh, S. V., Murin, I. V., Privalov, A. F., Pronkin, A. A., Rössler, E., & Vieth, H. M. (1998). Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data. Journal of Non-Crystalline Solids, 240(1-3), 79-90. https://doi.org/10.1016/S0022-3093(98)00702-9

Vancouver

Dvinskikh SV, Murin IV, Privalov AF, Pronkin AA, Rössler E, Vieth HM. Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data. Journal of Non-Crystalline Solids. 1998 Окт. 2;240(1-3):79-90. https://doi.org/10.1016/S0022-3093(98)00702-9

Author

Dvinskikh, S. V. ; Murin, I. V. ; Privalov, A. F. ; Pronkin, A. A. ; Rössler, E. ; Vieth, H. M. / Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data. в: Journal of Non-Crystalline Solids. 1998 ; Том 240, № 1-3. стр. 79-90.

BibTeX

@article{a4cc9587d6a5430b916a50d02dbe6cc7,
title = "Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data",
abstract = "The structure of phosphate glasses of the nominal composition x·LiF + (1 - x)·LiPO3 has been studied for 0 < x < 0.35, using 1H, 7Li, 19F, 31P NMR. By combining data from different nuclei and various solid state NMR techniques structural information on the molecular scale is obtained. The measurements confirm that the structural units of the glass are polyphosphate chains, and allow determination of their average length. The increase of LiF concentration, x, from 0 to 0.35 leads to a shortening of the chains from 29 to 4 phosphate units by use of Li and F to form terminal groups. Fluorine is partitioned between two structural units: fluorophosphate terminal groups and Li+F- fragments, in a ratio of about 1:1 at low x and decreasing to 1:4 at high x. Substantial loss of fluorine during glass preparation is observed and measured.",
author = "Dvinskikh, {S. V.} and Murin, {I. V.} and Privalov, {A. F.} and Pronkin, {A. A.} and E. R{\"o}ssler and Vieth, {H. M.}",
year = "1998",
month = oct,
day = "2",
doi = "10.1016/S0022-3093(98)00702-9",
language = "English",
volume = "240",
pages = "79--90",
journal = "Journal of Non-Crystalline Solids",
issn = "0022-3093",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - Microscopic structure of the glassy ionic conductor x · LiF + (1 - x) · LiPO3 from NMR data

AU - Dvinskikh, S. V.

AU - Murin, I. V.

AU - Privalov, A. F.

AU - Pronkin, A. A.

AU - Rössler, E.

AU - Vieth, H. M.

PY - 1998/10/2

Y1 - 1998/10/2

N2 - The structure of phosphate glasses of the nominal composition x·LiF + (1 - x)·LiPO3 has been studied for 0 < x < 0.35, using 1H, 7Li, 19F, 31P NMR. By combining data from different nuclei and various solid state NMR techniques structural information on the molecular scale is obtained. The measurements confirm that the structural units of the glass are polyphosphate chains, and allow determination of their average length. The increase of LiF concentration, x, from 0 to 0.35 leads to a shortening of the chains from 29 to 4 phosphate units by use of Li and F to form terminal groups. Fluorine is partitioned between two structural units: fluorophosphate terminal groups and Li+F- fragments, in a ratio of about 1:1 at low x and decreasing to 1:4 at high x. Substantial loss of fluorine during glass preparation is observed and measured.

AB - The structure of phosphate glasses of the nominal composition x·LiF + (1 - x)·LiPO3 has been studied for 0 < x < 0.35, using 1H, 7Li, 19F, 31P NMR. By combining data from different nuclei and various solid state NMR techniques structural information on the molecular scale is obtained. The measurements confirm that the structural units of the glass are polyphosphate chains, and allow determination of their average length. The increase of LiF concentration, x, from 0 to 0.35 leads to a shortening of the chains from 29 to 4 phosphate units by use of Li and F to form terminal groups. Fluorine is partitioned between two structural units: fluorophosphate terminal groups and Li+F- fragments, in a ratio of about 1:1 at low x and decreasing to 1:4 at high x. Substantial loss of fluorine during glass preparation is observed and measured.

UR - http://www.scopus.com/inward/record.url?scp=0032475641&partnerID=8YFLogxK

U2 - 10.1016/S0022-3093(98)00702-9

DO - 10.1016/S0022-3093(98)00702-9

M3 - Article

AN - SCOPUS:0032475641

VL - 240

SP - 79

EP - 90

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

SN - 0022-3093

IS - 1-3

ER -

ID: 88059992