Microemulsion Preconcentration of Steroid Hormones from Aqueous Solutions and Urine Samples

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Microemulsion Preconcentration of Steroid Hormones from Aqueous Solutions and Urine Samples. / Kartsova, L. A.; Solov’eva, S. A.; Bessonova, E. A.

в: Journal of Analytical Chemistry, Том 76, № 9, 01.09.2021, стр. 1058-1064.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{c6ded95f445140e0b94edd3968dd4900,

title = "Microemulsion Preconcentration of Steroid Hormones from Aqueous Solutions and Urine Samples",

abstract = "Abstract: A possibility of using an oil-in-water microemulsion of the composition 3% of sodium dodecyl sulfate, 8% of n-butanol, 1% of ethyl acetate, and 88% of water (by weight) as an extractant for the extraction and preconcentration of steroid hormones cortisol, cortisone, corticosterone, 11-deoxycortisol, and 11‑deoxycorticosterone from aqueous solutions and urine samples followed by their reversed-phase HPLC analysis with spectrophotometric detection is shown. In optimizing the extraction conditions, the nature of the oil, the time and temperature of extraction, and the time of the separation of the microemulsion were varied. Magnesium chloride was used to destroy the microemulsion. The concentration factors for steroid hormones increase with an increase in the hydrophobicity of the analytes. The limits of detection for steroids were 0.5–3 ng/mL, and concentration factors were 8–20.",

keywords = "microemulsion preconcentration, oil-in-water microemulsion, reversed-phase HPLC, steroid hormones, surfactants, EXTRACTION, SOLUBLE VITAMINS, SURFACTANTS, MICELLAR ELECTROKINETIC CHROMATOGRAPHY, SEPARATION, CORTICOSTEROIDS, CO",

author = "Kartsova, {L. A.} and Solov{\textquoteright}eva, {S. A.} and Bessonova, {E. A.}",

note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = sep,

day = "1",

doi = "10.1134/s1061934821090057",

language = "English",

volume = "76",

pages = "1058--1064",

journal = "Journal of Analytical Chemistry",

issn = "1061-9348",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "9",

}

RIS

TY - JOUR

T1 - Microemulsion Preconcentration of Steroid Hormones from Aqueous Solutions and Urine Samples

AU - Kartsova, L. A.

AU - Solov’eva, S. A.

AU - Bessonova, E. A.

PY - 2021/9/1

Y1 - 2021/9/1

N2 - Abstract: A possibility of using an oil-in-water microemulsion of the composition 3% of sodium dodecyl sulfate, 8% of n-butanol, 1% of ethyl acetate, and 88% of water (by weight) as an extractant for the extraction and preconcentration of steroid hormones cortisol, cortisone, corticosterone, 11-deoxycortisol, and 11‑deoxycorticosterone from aqueous solutions and urine samples followed by their reversed-phase HPLC analysis with spectrophotometric detection is shown. In optimizing the extraction conditions, the nature of the oil, the time and temperature of extraction, and the time of the separation of the microemulsion were varied. Magnesium chloride was used to destroy the microemulsion. The concentration factors for steroid hormones increase with an increase in the hydrophobicity of the analytes. The limits of detection for steroids were 0.5–3 ng/mL, and concentration factors were 8–20.

AB - Abstract: A possibility of using an oil-in-water microemulsion of the composition 3% of sodium dodecyl sulfate, 8% of n-butanol, 1% of ethyl acetate, and 88% of water (by weight) as an extractant for the extraction and preconcentration of steroid hormones cortisol, cortisone, corticosterone, 11-deoxycortisol, and 11‑deoxycorticosterone from aqueous solutions and urine samples followed by their reversed-phase HPLC analysis with spectrophotometric detection is shown. In optimizing the extraction conditions, the nature of the oil, the time and temperature of extraction, and the time of the separation of the microemulsion were varied. Magnesium chloride was used to destroy the microemulsion. The concentration factors for steroid hormones increase with an increase in the hydrophobicity of the analytes. The limits of detection for steroids were 0.5–3 ng/mL, and concentration factors were 8–20.

KW - microemulsion preconcentration

KW - oil-in-water microemulsion

KW - reversed-phase HPLC

KW - steroid hormones

KW - surfactants

KW - EXTRACTION

KW - SOLUBLE VITAMINS

KW - SURFACTANTS

KW - MICELLAR ELECTROKINETIC CHROMATOGRAPHY

KW - SEPARATION

KW - CORTICOSTEROIDS

KW - CO

UR - http://www.scopus.com/inward/record.url?scp=85114395332&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b6296e39-03fd-385c-a5aa-edc80302429d/

U2 - 10.1134/s1061934821090057

DO - 10.1134/s1061934821090057

M3 - Article

AN - SCOPUS:85114395332

VL - 76

SP - 1058

EP - 1064

JO - Journal of Analytical Chemistry

JF - Journal of Analytical Chemistry

SN - 1061-9348

IS - 9

ER -

ID: 87878716