TY - JOUR

T1 - Microcrystalline Luminescent (Eu1-xLnx)2bdc3·nH2O (Ln = La, Gd, Lu) Antenna MOFs: Effect of Dopant Content on Structure, Particle Morphology, and Luminescent Properties

AU - Колесник, Стефания Сергеевна

AU - Богачев, Никита Александрович

AU - Колесников, Илья Евгеньевич

AU - Орлов, Сергей Николаевич

AU - Рязанцев, Михаил Николаевич

AU - Gonzalez, Gema

AU - Скрипкин, Михаил Юрьевич

AU - Мерещенко, Андрей Сергеевич

PY - 2024/1/21

Y1 - 2024/1/21

N2 - In this work, three series of micro-sized heterometallic europium-containing terephthalate MOFs, (Eu 1-xLn x) 2bdc 3·nH 2O (Ln = La, Gd, Lu), are synthesized via an ultrasound-assisted method in an aqueous medium. La 3+ and Gd 3+-doped terephthalates are isostructural to Eu 2bdc 3·4H 2O. Lu 3+-doped compounds are isostructural to Eu 2bdc 3·4H 2O with Lu contents lower than 95 at.%. The compounds that are isostructural to Lu 2bdc 3·2.5H 2O are formed at higher Lu 3+ concentrations for the (Eu 1-xLu x) 2bdc 3·nH 2O series. All materials consist of micrometer-sized particles. The particle shape is determined by the crystalline phase. All the synthesized samples demonstrate an "antenna" effect: a bright-red emission corresponding to the 5D 0- 7F J transitions of Eu 3+ ions is observed upon 310 nm excitation into the singlet electronic excited state of terephthalate ions. The fine structure of the emission spectra is determined by the crystalline phase due to the different local symmetries of the Eu 3+ ions in the different kinds of crystalline structures. The photoluminescence quantum yield and 5D 0 excited state lifetime of Eu 3+ are equal to 11 ± 2% and 0.44 ± 0.01 ms, respectively, for the Ln 2bdc 3·4H 2O structures. For the (Eu 1-xLu x) 2bdc 3·2.5H 2O compounds, significant increases in the photoluminescence quantum yield and 5D 0 excited state lifetime of Eu 3+ are observed, reaching 23% and 1.62 ms, respectively.

AB - In this work, three series of micro-sized heterometallic europium-containing terephthalate MOFs, (Eu 1-xLn x) 2bdc 3·nH 2O (Ln = La, Gd, Lu), are synthesized via an ultrasound-assisted method in an aqueous medium. La 3+ and Gd 3+-doped terephthalates are isostructural to Eu 2bdc 3·4H 2O. Lu 3+-doped compounds are isostructural to Eu 2bdc 3·4H 2O with Lu contents lower than 95 at.%. The compounds that are isostructural to Lu 2bdc 3·2.5H 2O are formed at higher Lu 3+ concentrations for the (Eu 1-xLu x) 2bdc 3·nH 2O series. All materials consist of micrometer-sized particles. The particle shape is determined by the crystalline phase. All the synthesized samples demonstrate an "antenna" effect: a bright-red emission corresponding to the 5D 0- 7F J transitions of Eu 3+ ions is observed upon 310 nm excitation into the singlet electronic excited state of terephthalate ions. The fine structure of the emission spectra is determined by the crystalline phase due to the different local symmetries of the Eu 3+ ions in the different kinds of crystalline structures. The photoluminescence quantum yield and 5D 0 excited state lifetime of Eu 3+ are equal to 11 ± 2% and 0.44 ± 0.01 ms, respectively, for the Ln 2bdc 3·4H 2O structures. For the (Eu 1-xLu x) 2bdc 3·2.5H 2O compounds, significant increases in the photoluminescence quantum yield and 5D 0 excited state lifetime of Eu 3+ are observed, reaching 23% and 1.62 ms, respectively.

KW - europium

KW - gadolinium

KW - lanthanum

KW - luminescence

KW - lutetium

KW - metal–organic framework

KW - microcrystals

KW - rare earth

KW - ultrasound

UR - https://www.mendeley.com/catalogue/4a07379d-1097-3655-aab5-c905509a2aee/

U2 - 10.3390/molecules29020532

DO - 10.3390/molecules29020532

M3 - Article

C2 - 38276610

VL - 29

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 2

M1 - 532

ER -