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DOI

The first representative of the aziridine-fused benzo[e][1,4]thiazine series was synthesized from methyl 2-bromo-2-phenyl-2H-azirine-2-carboxylate and benzo[d]thiazole in 74% yield. The reaction proceeds via the SN2′-SN2′-cascade to form the azirinylthiazolium salt followed by a water-induced thiazole ring expansion. The structure of the title compound was established based on 1H, 13C, 2D NMR spectroscopy and high-resolution mass spectrometry, and unambiguously confirmed by X-ray diffraction analysis.
Язык оригиналаанглийский
Номер статьиM2101
Число страниц5
ЖурналMolBank
Том2025
Номер выпуска4
DOI
СостояниеОпубликовано - 4 дек 2025

ID: 145303812