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Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups : chain rigidity, molecular and thin film properties. / Yevlampieva, Natalia; Bermeshev, Maxim; Vezo, Olga; Chapala, Pavel; Il'yasova, Yulia.

в: Journal of Polymer Research, Том 25, № 8, 162, 02.07.2018.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Yevlampieva, N, Bermeshev, M, Vezo, O, Chapala, P & Il'yasova, Y 2018, 'Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups: chain rigidity, molecular and thin film properties', Journal of Polymer Research, Том. 25, № 8, 162. https://doi.org/10.1007/s10965-018-1558-7

APA

Yevlampieva, N., Bermeshev, M., Vezo, O., Chapala, P., & Il'yasova, Y. (2018). Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups: chain rigidity, molecular and thin film properties. Journal of Polymer Research, 25(8), [162]. https://doi.org/10.1007/s10965-018-1558-7

Vancouver

Yevlampieva N, Bermeshev M, Vezo O, Chapala P, Il'yasova Y. Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups: chain rigidity, molecular and thin film properties. Journal of Polymer Research. 2018 Июль 2;25(8). 162. https://doi.org/10.1007/s10965-018-1558-7

Author

Yevlampieva, Natalia ; Bermeshev, Maxim ; Vezo, Olga ; Chapala, Pavel ; Il'yasova, Yulia. / Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups : chain rigidity, molecular and thin film properties. в: Journal of Polymer Research. 2018 ; Том 25, № 8.

BibTeX

@article{5a1aa6db09a44bc081c58023f2b5c097,
title = "Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups: chain rigidity, molecular and thin film properties",
abstract = "A set of poly[bis(trimethylsilyl) tricyclononenes] bearing two trimethylsilyl side groups at geminal position in monomer unit has been synthesized by ring-opening metathesis polymerization technique and investigated via static and dynamic light scattering, viscometry and H-1 NMR relaxation in diluted solutions. Molecular properties of this type polymer have been under study for the first time. Its scaling relations and chain rigidity are obtained and compared to polymer synthesized by means of addition polymerization of the same monomer. There is shown that additive and metathesis polymers considerably differ by their chain rigidity, both equilibrium and kinetic. Metathesis analogue is typical flexible chain polymer characterizing by Kuhn segment length 1.6 nm, while the additive one, whose Kuhn segment is 5.6 nm, belongs to semirigid range. The influence of chain rigidity on thin film properties of substituted polytricyclononenes is also discussed because the synthesized by addition or metathesis routes polymers display very different gas permeability in films.",
keywords = "Poly(tricyclononenes), Metathesis ring-opening polymerizations, Solution properties, Structure-property relations, MONOMER UNIT, TRICYCLONONENES, POLYNORBORNENES, ME3SI",
author = "Natalia Yevlampieva and Maxim Bermeshev and Olga Vezo and Pavel Chapala and Yulia Il'yasova",
year = "2018",
month = jul,
day = "2",
doi = "10.1007/s10965-018-1558-7",
language = "Английский",
volume = "25",
journal = "Journal of Polymer Research",
issn = "1022-9760",
publisher = "Springer Nature",
number = "8",

}

RIS

TY - JOUR

T1 - Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups

T2 - chain rigidity, molecular and thin film properties

AU - Yevlampieva, Natalia

AU - Bermeshev, Maxim

AU - Vezo, Olga

AU - Chapala, Pavel

AU - Il'yasova, Yulia

PY - 2018/7/2

Y1 - 2018/7/2

N2 - A set of poly[bis(trimethylsilyl) tricyclononenes] bearing two trimethylsilyl side groups at geminal position in monomer unit has been synthesized by ring-opening metathesis polymerization technique and investigated via static and dynamic light scattering, viscometry and H-1 NMR relaxation in diluted solutions. Molecular properties of this type polymer have been under study for the first time. Its scaling relations and chain rigidity are obtained and compared to polymer synthesized by means of addition polymerization of the same monomer. There is shown that additive and metathesis polymers considerably differ by their chain rigidity, both equilibrium and kinetic. Metathesis analogue is typical flexible chain polymer characterizing by Kuhn segment length 1.6 nm, while the additive one, whose Kuhn segment is 5.6 nm, belongs to semirigid range. The influence of chain rigidity on thin film properties of substituted polytricyclononenes is also discussed because the synthesized by addition or metathesis routes polymers display very different gas permeability in films.

AB - A set of poly[bis(trimethylsilyl) tricyclononenes] bearing two trimethylsilyl side groups at geminal position in monomer unit has been synthesized by ring-opening metathesis polymerization technique and investigated via static and dynamic light scattering, viscometry and H-1 NMR relaxation in diluted solutions. Molecular properties of this type polymer have been under study for the first time. Its scaling relations and chain rigidity are obtained and compared to polymer synthesized by means of addition polymerization of the same monomer. There is shown that additive and metathesis polymers considerably differ by their chain rigidity, both equilibrium and kinetic. Metathesis analogue is typical flexible chain polymer characterizing by Kuhn segment length 1.6 nm, while the additive one, whose Kuhn segment is 5.6 nm, belongs to semirigid range. The influence of chain rigidity on thin film properties of substituted polytricyclononenes is also discussed because the synthesized by addition or metathesis routes polymers display very different gas permeability in films.

KW - Poly(tricyclononenes)

KW - Metathesis ring-opening polymerizations

KW - Solution properties

KW - Structure-property relations

KW - MONOMER UNIT

KW - TRICYCLONONENES

KW - POLYNORBORNENES

KW - ME3SI

U2 - 10.1007/s10965-018-1558-7

DO - 10.1007/s10965-018-1558-7

M3 - статья

VL - 25

JO - Journal of Polymer Research

JF - Journal of Polymer Research

SN - 1022-9760

IS - 8

M1 - 162

ER -

ID: 37251710