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Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview). / Bolotin, Dmitrii S.; Rassadin, Valentin A.; Bokach, Nadezhda A.; Kukushkin, Vadim Yu.

в: Inorganica Chimica Acta, Том 455P2, 2016, стр. 446-454.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Bolotin, DS, Rassadin, VA, Bokach, NA & Kukushkin, VY 2016, 'Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview)', Inorganica Chimica Acta, Том. 455P2, стр. 446-454. https://doi.org/10.1016/j.ica.2016.02.025

APA

Bolotin, D. S., Rassadin, V. A., Bokach, N. A., & Kukushkin, V. Y. (2016). Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview). Inorganica Chimica Acta, 455P2, 446-454. https://doi.org/10.1016/j.ica.2016.02.025

Vancouver

Bolotin DS, Rassadin VA, Bokach NA, Kukushkin VY. Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview). Inorganica Chimica Acta. 2016;455P2:446-454. https://doi.org/10.1016/j.ica.2016.02.025

Author

Bolotin, Dmitrii S. ; Rassadin, Valentin A. ; Bokach, Nadezhda A. ; Kukushkin, Vadim Yu. / Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview). в: Inorganica Chimica Acta. 2016 ; Том 455P2. стр. 446-454.

BibTeX

@article{f8b4e175648c4ba5accbac2f37a77d9d,
title = "Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview)",
abstract = "This review is focused on progress in the area of metal-involving reactions of cyanamides leading to aminosubstituted heterocycles. The consideration covers metal-mediated cyanamide–amidoxime coupling giving 5-aminosubstituted 1,2,4-oxadiazoles and cycloaddition of nitrones or azides to cyanamide species furnishing 5-aminosubstituted 2,3-dihydro-1,2,4-oxadiazoles and 5-aminotetrazoles, respectively. Gold-catalyzed heterocyclization of cyanamides and acetylenes providing 2-aminooxazole systems is also considered. All these reaction schemes are discussed from viewpoints of sustainable processes with particular focus on how application of metal-involving reactions to organic transformations of cyanamides provides milder reaction conditions, increase yields of target products, and reduce number of reactions steps thus making the chemistry of cyanamides more environmentally benign.",
keywords = "CyanamidesMetal-involving reactionsN-Substituted heterocycles1-3-Dipolar cycloadditionNucleophilic additionSustainable chemistry",
author = "Bolotin, {Dmitrii S.} and Rassadin, {Valentin A.} and Bokach, {Nadezhda A.} and Kukushkin, {Vadim Yu.}",
year = "2016",
doi = "10.1016/j.ica.2016.02.025",
language = "не определен",
volume = "455P2",
pages = "446--454",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview)

AU - Bolotin, Dmitrii S.

AU - Rassadin, Valentin A.

AU - Bokach, Nadezhda A.

AU - Kukushkin, Vadim Yu.

PY - 2016

Y1 - 2016

N2 - This review is focused on progress in the area of metal-involving reactions of cyanamides leading to aminosubstituted heterocycles. The consideration covers metal-mediated cyanamide–amidoxime coupling giving 5-aminosubstituted 1,2,4-oxadiazoles and cycloaddition of nitrones or azides to cyanamide species furnishing 5-aminosubstituted 2,3-dihydro-1,2,4-oxadiazoles and 5-aminotetrazoles, respectively. Gold-catalyzed heterocyclization of cyanamides and acetylenes providing 2-aminooxazole systems is also considered. All these reaction schemes are discussed from viewpoints of sustainable processes with particular focus on how application of metal-involving reactions to organic transformations of cyanamides provides milder reaction conditions, increase yields of target products, and reduce number of reactions steps thus making the chemistry of cyanamides more environmentally benign.

AB - This review is focused on progress in the area of metal-involving reactions of cyanamides leading to aminosubstituted heterocycles. The consideration covers metal-mediated cyanamide–amidoxime coupling giving 5-aminosubstituted 1,2,4-oxadiazoles and cycloaddition of nitrones or azides to cyanamide species furnishing 5-aminosubstituted 2,3-dihydro-1,2,4-oxadiazoles and 5-aminotetrazoles, respectively. Gold-catalyzed heterocyclization of cyanamides and acetylenes providing 2-aminooxazole systems is also considered. All these reaction schemes are discussed from viewpoints of sustainable processes with particular focus on how application of metal-involving reactions to organic transformations of cyanamides provides milder reaction conditions, increase yields of target products, and reduce number of reactions steps thus making the chemistry of cyanamides more environmentally benign.

KW - CyanamidesMetal-involving reactionsN-Substituted heterocycles1-3-Dipolar cycloadditionNucleophilic additionSustainable chemistry

U2 - 10.1016/j.ica.2016.02.025

DO - 10.1016/j.ica.2016.02.025

M3 - статья

VL - 455P2

SP - 446

EP - 454

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 7569089