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Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering. / Иванов, Даниил Михайлович; Бокач, Надежда Арсеньевна; Кукушкин, Вадим Юрьевич; Frontera, Antonio.

в: Chemistry - A European Journal, 29.10.2021.

Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование

Harvard

Иванов, ДМ, Бокач, НА, Кукушкин, ВЮ & Frontera, A 2021, 'Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering', Chemistry - A European Journal. https://doi.org/10.1002/chem.202103173

APA

Иванов, Д. М., Бокач, Н. А., Кукушкин, В. Ю., & Frontera, A. (2021). Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering. Chemistry - A European Journal. https://doi.org/10.1002/chem.202103173

Vancouver

Иванов ДМ, Бокач НА, Кукушкин ВЮ, Frontera A. Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering. Chemistry - A European Journal. 2021 Окт. 29. https://doi.org/10.1002/chem.202103173

Author

Иванов, Даниил Михайлович ; Бокач, Надежда Арсеньевна ; Кукушкин, Вадим Юрьевич ; Frontera, Antonio. / Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering. в: Chemistry - A European Journal. 2021.

BibTeX

@article{9abe07c1ab25482c93e9a88a60289604,
title = "Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering",
abstract = "This review highlights recent studies discovering unconventional halogen bonding (HaB) that involves positively charged metal centers. These centers provide their filled d-orbitals for HaB, and thus behave as nucleophilic components toward the noncovalent interaction. This role of some electron-rich transition metal centers can be considered an oxymoron in the sense that the metal is, in most cases, formally cationic; consequently, its electron donor function is unexpected. The importance of Ha⋅⋅⋅d-[M] (Ha=halogen; M is Group 9 (Rh, Ir), 10 (Ni, Pd, Pt), or 11 (Cu, Au)) interactions in crystal engineering is emphasized by showing remarkable examples (reported and uncovered by our processing of the Cambridge Structural Database), where this Ha⋅⋅⋅d-[M] directional interaction guides the formation of solid supramolecular assemblies of different dimensionalities.",
keywords = "halogen bonding, noncovalent interactions, nucleophilic metal centers, theoretical calculations, σ-hole interactions, PLATINUM ACETYLACETONATE, COMPLEXES, IODINE, NONCOVALENT INTERACTIONS, CHALCOGEN, HYDROGEN-BONDS, sigma-hole interactions, REDOX REACTION, OXIDATIVE-ADDITION, ARYL IODIDES, LIGAND",
author = "Иванов, {Даниил Михайлович} and Бокач, {Надежда Арсеньевна} and Кукушкин, {Вадим Юрьевич} and Antonio Frontera",
note = "Publisher Copyright: {\textcopyright} 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH",
year = "2021",
month = oct,
day = "29",
doi = "10.1002/chem.202103173",
language = "English",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",

}

RIS

TY - JOUR

T1 - Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering

AU - Иванов, Даниил Михайлович

AU - Бокач, Надежда Арсеньевна

AU - Кукушкин, Вадим Юрьевич

AU - Frontera, Antonio

N1 - Publisher Copyright: © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH

PY - 2021/10/29

Y1 - 2021/10/29

N2 - This review highlights recent studies discovering unconventional halogen bonding (HaB) that involves positively charged metal centers. These centers provide their filled d-orbitals for HaB, and thus behave as nucleophilic components toward the noncovalent interaction. This role of some electron-rich transition metal centers can be considered an oxymoron in the sense that the metal is, in most cases, formally cationic; consequently, its electron donor function is unexpected. The importance of Ha⋅⋅⋅d-[M] (Ha=halogen; M is Group 9 (Rh, Ir), 10 (Ni, Pd, Pt), or 11 (Cu, Au)) interactions in crystal engineering is emphasized by showing remarkable examples (reported and uncovered by our processing of the Cambridge Structural Database), where this Ha⋅⋅⋅d-[M] directional interaction guides the formation of solid supramolecular assemblies of different dimensionalities.

AB - This review highlights recent studies discovering unconventional halogen bonding (HaB) that involves positively charged metal centers. These centers provide their filled d-orbitals for HaB, and thus behave as nucleophilic components toward the noncovalent interaction. This role of some electron-rich transition metal centers can be considered an oxymoron in the sense that the metal is, in most cases, formally cationic; consequently, its electron donor function is unexpected. The importance of Ha⋅⋅⋅d-[M] (Ha=halogen; M is Group 9 (Rh, Ir), 10 (Ni, Pd, Pt), or 11 (Cu, Au)) interactions in crystal engineering is emphasized by showing remarkable examples (reported and uncovered by our processing of the Cambridge Structural Database), where this Ha⋅⋅⋅d-[M] directional interaction guides the formation of solid supramolecular assemblies of different dimensionalities.

KW - halogen bonding

KW - noncovalent interactions

KW - nucleophilic metal centers

KW - theoretical calculations

KW - σ-hole interactions

KW - PLATINUM ACETYLACETONATE

KW - COMPLEXES

KW - IODINE

KW - NONCOVALENT INTERACTIONS

KW - CHALCOGEN

KW - HYDROGEN-BONDS

KW - sigma-hole interactions

KW - REDOX REACTION

KW - OXIDATIVE-ADDITION

KW - ARYL IODIDES

KW - LIGAND

UR - http://www.scopus.com/inward/record.url?scp=85118339957&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/9f1ac522-73a6-3e40-b144-853496cf6e06/

U2 - 10.1002/chem.202103173

DO - 10.1002/chem.202103173

M3 - Review article

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

ER -

ID: 86295496