Результаты исследований: Научные публикации в периодических изданиях › статья
Mass-resolved two-photon and photoelectron spectra of ArXe in the region of Xe∗ 7p, 6p, 6d. / Rakcheeva, L.P.; Serdobintsev, P.Y.; Belyaeva, A.A.; Shevkunov, I.A.; Melnikov, A.S.; Nakozina, A.A.; Pastor, A.A.; Khodorkovskii, M.A.
в: Journal of Chemical Physics, Том 139, № 17, 2013, стр. 174304.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Mass-resolved two-photon and photoelectron spectra of ArXe in the region of Xe∗ 7p, 6p, 6d
AU - Rakcheeva, L.P.
AU - Serdobintsev, P.Y.
AU - Belyaeva, A.A.
AU - Shevkunov, I.A.
AU - Melnikov, A.S.
AU - Nakozina, A.A.
AU - Pastor, A.A.
AU - Khodorkovskii, M.A.
PY - 2013
Y1 - 2013
N2 - The two photon resonant, three photon ionization spectra of ArXe were recorded in the spec- tral region of 88 500–90 100 cm−1. Seven new molecular band progressions dissociating to ArXe∗ → Ar1S0 + Xe∗ 7p[1/2]0, Xe∗ 7p[3/2]2, Xe∗ 6p been selected and analyzed. The molecular constants for the excited states of ArXe∗ of these vibra- tional progressions were determined in the approximation of the anharmonic oscillator, the Morse potential and the Franck-Condon principle. The photoelectron spectra were recorded by several excited electronic-vibrational transitions of ArXe, the dissociation channels of the excited molecules were determined and extra information about the electron structure of the excited molecular states was obtained.
AB - The two photon resonant, three photon ionization spectra of ArXe were recorded in the spec- tral region of 88 500–90 100 cm−1. Seven new molecular band progressions dissociating to ArXe∗ → Ar1S0 + Xe∗ 7p[1/2]0, Xe∗ 7p[3/2]2, Xe∗ 6p been selected and analyzed. The molecular constants for the excited states of ArXe∗ of these vibra- tional progressions were determined in the approximation of the anharmonic oscillator, the Morse potential and the Franck-Condon principle. The photoelectron spectra were recorded by several excited electronic-vibrational transitions of ArXe, the dissociation channels of the excited molecules were determined and extra information about the electron structure of the excited molecular states was obtained.
KW - two-photon excitation
KW - REMPI
KW - supersonic jet
KW - mass-spectroscopy
KW - electron spectroscopy
U2 - 10.1063/1.4827476
DO - 10.1063/1.4827476
M3 - Article
VL - 139
SP - 174304
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 17
ER -
ID: 7389740