Результаты исследований: Научные публикации в периодических изданиях › статья
Magnetic study of interatomic interactions, synthesis, structural and mass spectroscopy investigations of lanthanum gallate doped with cobalt and magnesium. / Korolev, D.A.; Chezhina, N.V.; Lopatin, S.I.
в: Journal of Alloys and Compounds, № 624, 2015, стр. 53-59.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Magnetic study of interatomic interactions, synthesis, structural and mass spectroscopy investigations of lanthanum gallate doped with cobalt and magnesium
AU - Korolev, D.A.
AU - Chezhina, N.V.
AU - Lopatin, S.I.
PY - 2015
Y1 - 2015
N2 - For the first time by X-ray method two phases of the solid solutions LaCoxGa1-1.2xMg0.2xO3-δ and LaCoxGa1-1.5xMg0.5xO3-δ (x = 0.01 − 0.10) with different structure were found – rhombohedral and orthorhombic phases. On the basis of the data on evaporation of the components a synthetic procedure was advanced allowing the losses of cobalt to be minimized. The study of magnetic characteristics of obtained solid solutions showed the formation of high nuclearity clusters containing cobalt atoms, and also magnesium and associated vacancies even in diluted solid solutions. Clusters are characterized by a competition between ferro- and antiferromagnetic exchange interactions, whereas the long order exchange is antiferromagnetic.
AB - For the first time by X-ray method two phases of the solid solutions LaCoxGa1-1.2xMg0.2xO3-δ and LaCoxGa1-1.5xMg0.5xO3-δ (x = 0.01 − 0.10) with different structure were found – rhombohedral and orthorhombic phases. On the basis of the data on evaporation of the components a synthetic procedure was advanced allowing the losses of cobalt to be minimized. The study of magnetic characteristics of obtained solid solutions showed the formation of high nuclearity clusters containing cobalt atoms, and also magnesium and associated vacancies even in diluted solid solutions. Clusters are characterized by a competition between ferro- and antiferromagnetic exchange interactions, whereas the long order exchange is antiferromagnetic.
KW - Ceramics
KW - Magnetic properties
KW - Powder diffraction
KW - Secondary ion mass spectroscopy (SMS)
U2 - 10.1016/j.jallcom.2014.11.086
DO - 10.1016/j.jallcom.2014.11.086
M3 - Article
SP - 53
EP - 59
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
IS - 624
ER -
ID: 3924725