Localization and Charge State of Metal Ions in Carbon Nanostructures of Europium Bis-Phthalocyanine Pyrolysed Derivatives

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Localization and Charge State of Metal Ions in Carbon Nanostructures of Europium Bis-Phthalocyanine Pyrolysed Derivatives. / Kozlov, V.S.; Semenov, V.G.; Bykov, A.A.; Bairamukov, V.Y.

в: Technical Physics, Том 69, № 7, 01.07.2024, стр. 2007-2013.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{60a0b2e929aa4ad6acda0ba198144cfe,

title = "Localization and Charge State of Metal Ions in Carbon Nanostructures of Europium Bis-Phthalocyanine Pyrolysed Derivatives",

abstract = "Abstract: In the experiments of M{\"o}ssbauer spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM) the morphology and structurization of the carbon phase, the charge state of europium and the dynamic properties of europium bis-phthalocyanine pyrolysed derivatives, including the Debye temperature, were revealed. It was found that the pyrolysis of europium bis-pthalocyanine resulted in the amorphous carbon matrix and nanoscaled graphene clusters both forming turbostratic carbon phase. The europium ions in the charge state Eu3+/Eu2+ were detected. The data indicated that localization of Eu ions took place between layers of graphenes similar to graphite intercalation compounds. It was shown that an isomeric shift, linewidths and the magnitude of the resonant absorption are essential characteristics of structural transformations at the pyrolysis of rare earth bis-phthalocyanines. {\textcopyright} Pleiades Publishing, Ltd. 2024. ISSN 1063-7842, Technical Physics, 2024, Vol. 69, No. 7, pp. 2007–2013. Pleiades Publishing, Ltd., 2024. Russian Text The Author(s), 2023, published in Zhurnal Tekhnicheskoi Fiziki, 2023, Vol. 93, No. 6, pp. 787–793. English Text Ioffe Institute, 2023.",

keywords = "bis-pthalocyanine, carbon nanocomposite, graphene clusters, intercalation, M{\"o}ssbauer spectroscopy, pyrolysis",

author = "V.S. Kozlov and V.G. Semenov and A.A. Bykov and V.Y. Bairamukov",

note = "Export Date: 21 October 2024 Адрес для корреспонденции: Bairamukov, V.Y.; St. Petersburg Nuclear Physics Institute, Russian Federation; эл. почта: bayramukov_vy@pnpi.nrcki.ru",

year = "2024",

month = jul,

day = "1",

doi = "10.1134/s1063784224070223",

language = "Английский",

volume = "69",

pages = "2007--2013",

journal = "Technical Physics",

issn = "1063-7842",

publisher = "Pleiades Publishing",

number = "7",

}

RIS

TY - JOUR

T1 - Localization and Charge State of Metal Ions in Carbon Nanostructures of Europium Bis-Phthalocyanine Pyrolysed Derivatives

AU - Kozlov, V.S.

AU - Semenov, V.G.

AU - Bykov, A.A.

AU - Bairamukov, V.Y.

N1 - Export Date: 21 October 2024 Адрес для корреспонденции: Bairamukov, V.Y.; St. Petersburg Nuclear Physics Institute, Russian Federation; эл. почта: bayramukov_vy@pnpi.nrcki.ru

PY - 2024/7/1

Y1 - 2024/7/1

N2 - Abstract: In the experiments of Mössbauer spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM) the morphology and structurization of the carbon phase, the charge state of europium and the dynamic properties of europium bis-phthalocyanine pyrolysed derivatives, including the Debye temperature, were revealed. It was found that the pyrolysis of europium bis-pthalocyanine resulted in the amorphous carbon matrix and nanoscaled graphene clusters both forming turbostratic carbon phase. The europium ions in the charge state Eu3+/Eu2+ were detected. The data indicated that localization of Eu ions took place between layers of graphenes similar to graphite intercalation compounds. It was shown that an isomeric shift, linewidths and the magnitude of the resonant absorption are essential characteristics of structural transformations at the pyrolysis of rare earth bis-phthalocyanines. © Pleiades Publishing, Ltd. 2024. ISSN 1063-7842, Technical Physics, 2024, Vol. 69, No. 7, pp. 2007–2013. Pleiades Publishing, Ltd., 2024. Russian Text The Author(s), 2023, published in Zhurnal Tekhnicheskoi Fiziki, 2023, Vol. 93, No. 6, pp. 787–793. English Text Ioffe Institute, 2023.

AB - Abstract: In the experiments of Mössbauer spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM) the morphology and structurization of the carbon phase, the charge state of europium and the dynamic properties of europium bis-phthalocyanine pyrolysed derivatives, including the Debye temperature, were revealed. It was found that the pyrolysis of europium bis-pthalocyanine resulted in the amorphous carbon matrix and nanoscaled graphene clusters both forming turbostratic carbon phase. The europium ions in the charge state Eu3+/Eu2+ were detected. The data indicated that localization of Eu ions took place between layers of graphenes similar to graphite intercalation compounds. It was shown that an isomeric shift, linewidths and the magnitude of the resonant absorption are essential characteristics of structural transformations at the pyrolysis of rare earth bis-phthalocyanines. © Pleiades Publishing, Ltd. 2024. ISSN 1063-7842, Technical Physics, 2024, Vol. 69, No. 7, pp. 2007–2013. Pleiades Publishing, Ltd., 2024. Russian Text The Author(s), 2023, published in Zhurnal Tekhnicheskoi Fiziki, 2023, Vol. 93, No. 6, pp. 787–793. English Text Ioffe Institute, 2023.

KW - bis-pthalocyanine

KW - carbon nanocomposite

KW - graphene clusters

KW - intercalation

KW - Mössbauer spectroscopy

KW - pyrolysis

UR - https://www.mendeley.com/catalogue/7122605f-a171-3c82-8bd8-dae0e9c47605/

U2 - 10.1134/s1063784224070223

DO - 10.1134/s1063784224070223

M3 - статья

VL - 69

SP - 2007

EP - 2013

JO - Technical Physics

JF - Technical Physics

SN - 1063-7842

IS - 7

ER -

ID: 126224192