Standard

Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride. / Samarov, Artemiy; Shner, Natalia; Mozheeva, Ekaterina; Toikka, Alexander.

в: Journal of Chemical Thermodynamics, Том 131, 01.04.2019, стр. 369-374.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Samarov, A, Shner, N, Mozheeva, E & Toikka, A 2019, 'Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride', Journal of Chemical Thermodynamics, Том. 131, стр. 369-374. https://doi.org/10.1016/j.jct.2018.11.019

APA

Samarov, A., Shner, N., Mozheeva, E., & Toikka, A. (2019). Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride. Journal of Chemical Thermodynamics, 131, 369-374. https://doi.org/10.1016/j.jct.2018.11.019

Vancouver

Samarov A, Shner N, Mozheeva E, Toikka A. Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride. Journal of Chemical Thermodynamics. 2019 Апр. 1;131:369-374. https://doi.org/10.1016/j.jct.2018.11.019

Author

Samarov, Artemiy ; Shner, Natalia ; Mozheeva, Ekaterina ; Toikka, Alexander. / Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride. в: Journal of Chemical Thermodynamics. 2019 ; Том 131. стр. 369-374.

BibTeX

@article{dded61bc0f8d4daab1d4111c051c569c,
title = "Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride",
abstract = "The liquid-liquid equilibrium (LLE) for the mixtures of ethanol – ethyl propionate, n-propanol – n-propyl propionate and n-butanol – n-butyl propionate with deep eutectic solvents (DES) was studied. DES was used on the basis of choline chloride with malonic acid in a mole ratioof 1:1. The studies were carried out at two temperatures, 293.15 K and 313.15 K and atmospheric pressure. The compositions of the coexisting organic and DES phases were determined. On the basis of experimental data, alcohol distribution coefficient and selectivity were calculated and analysed. The effect of the temperature and length of the alcohol alkyl chain on the alcohol distribution coefficient and selectivity were established. Using the non-random two liquids model (NRTL), a thermodynamic simulation of obtained experimental data on the liquid-liquid phase equilibrium was carried out.",
keywords = "Choline chloride, Deep eutectic solvents, Liquid-liquid equilibria, NRTL, MIXTURES, EXTRACTION, MEDIA, SEPARATION, IONIC LIQUIDS, ENTRAINERS",
author = "Artemiy Samarov and Natalia Shner and Ekaterina Mozheeva and Alexander Toikka",
year = "2019",
month = apr,
day = "1",
doi = "10.1016/j.jct.2018.11.019",
language = "English",
volume = "131",
pages = "369--374",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride

AU - Samarov, Artemiy

AU - Shner, Natalia

AU - Mozheeva, Ekaterina

AU - Toikka, Alexander

PY - 2019/4/1

Y1 - 2019/4/1

N2 - The liquid-liquid equilibrium (LLE) for the mixtures of ethanol – ethyl propionate, n-propanol – n-propyl propionate and n-butanol – n-butyl propionate with deep eutectic solvents (DES) was studied. DES was used on the basis of choline chloride with malonic acid in a mole ratioof 1:1. The studies were carried out at two temperatures, 293.15 K and 313.15 K and atmospheric pressure. The compositions of the coexisting organic and DES phases were determined. On the basis of experimental data, alcohol distribution coefficient and selectivity were calculated and analysed. The effect of the temperature and length of the alcohol alkyl chain on the alcohol distribution coefficient and selectivity were established. Using the non-random two liquids model (NRTL), a thermodynamic simulation of obtained experimental data on the liquid-liquid phase equilibrium was carried out.

AB - The liquid-liquid equilibrium (LLE) for the mixtures of ethanol – ethyl propionate, n-propanol – n-propyl propionate and n-butanol – n-butyl propionate with deep eutectic solvents (DES) was studied. DES was used on the basis of choline chloride with malonic acid in a mole ratioof 1:1. The studies were carried out at two temperatures, 293.15 K and 313.15 K and atmospheric pressure. The compositions of the coexisting organic and DES phases were determined. On the basis of experimental data, alcohol distribution coefficient and selectivity were calculated and analysed. The effect of the temperature and length of the alcohol alkyl chain on the alcohol distribution coefficient and selectivity were established. Using the non-random two liquids model (NRTL), a thermodynamic simulation of obtained experimental data on the liquid-liquid phase equilibrium was carried out.

KW - Choline chloride

KW - Deep eutectic solvents

KW - Liquid-liquid equilibria

KW - NRTL

KW - MIXTURES

KW - EXTRACTION

KW - MEDIA

KW - SEPARATION

KW - IONIC LIQUIDS

KW - ENTRAINERS

UR - http://www.scopus.com/inward/record.url?scp=85057485188&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2018.11.019

DO - 10.1016/j.jct.2018.11.019

M3 - Article

AN - SCOPUS:85057485188

VL - 131

SP - 369

EP - 374

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

ER -

ID: 38490964