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Liquid-liquid equilibrium and critical states for the quaternary system propionic acid–n-butanol–n-butyl propionate–water at 303.15 K. / Тойкка, Мария Александровна; Trofimova, Dariya; Самаров, Артемий Андреевич.

в: Fluid Phase Equilibria, Том 460, 25.03.2018, стр. 17-22.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{cfb907110a884403976556a916a4350e,
title = "Liquid-liquid equilibrium and critical states for the quaternary system propionic acid–n-butanol–n-butyl propionate–water at 303.15 K",
abstract = "New experimental data on liquid-liquid equilibrium (LLE) and critical phases for the propionic acid – n-butanol – n-butyl propionate – water system at 303.15 K and atmospheric pressure are presented. The LLE compositions were determined by gas chromatography, correlated and predicted by NRTL and UNIFAC models respectively. The results of NRTL and UNIFAC modelling are in sufficient agreement with experimental data. Standard deviations for binary and ternary subsystems do not exceed 0.79% (NRTL) and 5.1% (UNIFAC). In case of quaternary system investigated σ(NRTL) = 0.56% and σ(UNIFAC) = 2.2%. The study of critical states was carried out by “cloud-point technique” method. The run of critical curve in quaternary system was studied.",
keywords = "Cloud-point technique, Critical states, Liquid-liquid equilibrium, n-butyl propionate, ESTERIFICATION, CATALYST, ACETIC-ACID, SOLUBILITY, MIXTURES, OIL, ESTERS, ETHANOL, 1-BUTANOL",
author = "Тойкка, {Мария Александровна} and Dariya Trofimova and Самаров, {Артемий Андреевич}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2018",
month = mar,
day = "25",
doi = "10.1016/j.fluid.2017.12.023",
language = "English",
volume = "460",
pages = "17--22",
journal = "Fluid Phase Equilibria",
issn = "0378-3812",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Liquid-liquid equilibrium and critical states for the quaternary system propionic acid–n-butanol–n-butyl propionate–water at 303.15 K

AU - Тойкка, Мария Александровна

AU - Trofimova, Dariya

AU - Самаров, Артемий Андреевич

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2018/3/25

Y1 - 2018/3/25

N2 - New experimental data on liquid-liquid equilibrium (LLE) and critical phases for the propionic acid – n-butanol – n-butyl propionate – water system at 303.15 K and atmospheric pressure are presented. The LLE compositions were determined by gas chromatography, correlated and predicted by NRTL and UNIFAC models respectively. The results of NRTL and UNIFAC modelling are in sufficient agreement with experimental data. Standard deviations for binary and ternary subsystems do not exceed 0.79% (NRTL) and 5.1% (UNIFAC). In case of quaternary system investigated σ(NRTL) = 0.56% and σ(UNIFAC) = 2.2%. The study of critical states was carried out by “cloud-point technique” method. The run of critical curve in quaternary system was studied.

AB - New experimental data on liquid-liquid equilibrium (LLE) and critical phases for the propionic acid – n-butanol – n-butyl propionate – water system at 303.15 K and atmospheric pressure are presented. The LLE compositions were determined by gas chromatography, correlated and predicted by NRTL and UNIFAC models respectively. The results of NRTL and UNIFAC modelling are in sufficient agreement with experimental data. Standard deviations for binary and ternary subsystems do not exceed 0.79% (NRTL) and 5.1% (UNIFAC). In case of quaternary system investigated σ(NRTL) = 0.56% and σ(UNIFAC) = 2.2%. The study of critical states was carried out by “cloud-point technique” method. The run of critical curve in quaternary system was studied.

KW - Cloud-point technique

KW - Critical states

KW - Liquid-liquid equilibrium

KW - n-butyl propionate

KW - ESTERIFICATION

KW - CATALYST

KW - ACETIC-ACID

KW - SOLUBILITY

KW - MIXTURES

KW - OIL

KW - ESTERS

KW - ETHANOL

KW - 1-BUTANOL

UR - https://www.sciencedirect.com/science/article/pii/S0378381217305071

UR - http://www.scopus.com/inward/record.url?scp=85039732681&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/liquidliquid-equilibrium-critical-states-quaternary-system-propionic-acidnbutanolnbutyl-propionatewa

U2 - 10.1016/j.fluid.2017.12.023

DO - 10.1016/j.fluid.2017.12.023

M3 - Article

VL - 460

SP - 17

EP - 22

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

SN - 0378-3812

ER -

ID: 11784668