The spectra of CH4-He mixtures were measured in the P- and R-region of v3 vibration-rotation band at lower pressures of 0.26-1.0 bar and for the whole band at higher pressures up to 90 bar. The broadening line coefficients were found from lower pressure data for the lines of P branch. These coefficients were calculated in the frame of the semi-classical approach. They agree with the experimental values, but a small J-dependent deviation was observed. The line mixing effect was observed. At higher pressure it was interpreted in the terms of the adjusted branch-coupling model. At lower pressure the line mixing effect was found to be especially pronounced in the region of relatively weak lines forming the clusters R(16) - R(19).

Язык оригиналаанглийский
Страницы (с-по)212-216
Число страниц5
ЖурналProceedings of SPIE - The International Society for Optical Engineering
Том4063
СостояниеОпубликовано - 1 янв 2000
Событие13th Symposium and School on High-Resolution Molecular Spectroscopy - Tomsk, Russia
Продолжительность: 4 июл 19996 июл 1999

    Предметные области Scopus

  • Электротехника и электроника
  • Физика конденсатов

ID: 35917711