TY - JOUR

T1 - Lewis acid/base stabilized phosphanylalane and -gallane

AU - Vogel, Ulf

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

PY - 2001/12/3

Y1 - 2001/12/3

N2 - Neither synthesis nor detection in matrix isolation experiments has been accomplished for the parent compounds of phosphanylalanes and -gallanes of type A. H2 elimination reactions between [(CO)5WPH3] and H3ENMe3 (E=Al, Ga) have enabled the first synthesis of Lewis acid/base stabilized complexes of the type B. Comprehensive density functional theory (DFT) calculations on the aluminum systems verify the high stability of the complexes of type B.

AB - Neither synthesis nor detection in matrix isolation experiments has been accomplished for the parent compounds of phosphanylalanes and -gallanes of type A. H2 elimination reactions between [(CO)5WPH3] and H3ENMe3 (E=Al, Ga) have enabled the first synthesis of Lewis acid/base stabilized complexes of the type B. Comprehensive density functional theory (DFT) calculations on the aluminum systems verify the high stability of the complexes of type B.

KW - Aluminum

KW - Density functional calculations

KW - Gallium

KW - Lewis acids

KW - Phosphorus

UR - http://www.scopus.com/inward/record.url?scp=0035803648&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20011203)40:23<4409::AID-ANIE4409>3.0.CO;2-F

DO - 10.1002/1521-3773(20011203)40:23<4409::AID-ANIE4409>3.0.CO;2-F

M3 - Article

VL - 40

SP - 4409

EP - 4412

JO - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

JF - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN - 1433-7851

IS - 23

ER -