Kinetics of micellisation and relaxation of cylindrical micelles described by the difference Becker-Döring equation

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Kinetics of micellisation and relaxation of cylindrical micelles described by the difference Becker-Döring equation. / Babintsev, I.A.; Adzhemyan, L.Ts.; Shchekin, A.K.

в: Soft Matter, Том 10, № 15, 2014, стр. 2619-2631.

Результаты исследований: Научные публикации в периодических изданиях › статья

BibTeX

@article{827afae03a1341b0896a9e34234830dd,

title = "Kinetics of micellisation and relaxation of cylindrical micelles described by the difference Becker-D{\"o}ring equation",

abstract = "A numerical description of micellisation and relaxation to an aggregate equilibrium in nonionic surfactant solution with spherical premicellar aggregates and stable polydisperse cylindrical micelles is presented for wide interval of total surfactant concentrations and initial conditions. The Smoluchowsky-type model for the attachment-detachment rates of surfactant monomers to and from surfactant aggregates with matching the rates for small spherical premicellar aggregates and the rates for larger cylindrical micelles have been used. The full discrete spectrum of characteristic times of micellar relaxation and first three relaxation modes in their dependence on equilibrium monomer concentration have been computed with using the linearized form of the Becker-D{\"o}ring difference equations. Overall time behavior of surfactant monomer and aggregate concentrations in micellisation and relaxation at large initial deviations from final equilibrium has been studied with the help of nonlinearized discrete Becker-D{\"o}ring k",

keywords = "micelle kinetics relaxation",

author = "I.A. Babintsev and L.Ts. Adzhemyan and A.K. Shchekin",

year = "2014",

doi = "10.1039/c3sm52460d",

language = "English",

volume = "10",

pages = "2619--2631",

journal = "Soft Matter",

issn = "1744-683X",

publisher = "Royal Society of Chemistry",

number = "15",

}

RIS

TY - JOUR

T1 - Kinetics of micellisation and relaxation of cylindrical micelles described by the difference Becker-Döring equation

AU - Babintsev, I.A.

AU - Adzhemyan, L.Ts.

AU - Shchekin, A.K.

PY - 2014

Y1 - 2014

N2 - A numerical description of micellisation and relaxation to an aggregate equilibrium in nonionic surfactant solution with spherical premicellar aggregates and stable polydisperse cylindrical micelles is presented for wide interval of total surfactant concentrations and initial conditions. The Smoluchowsky-type model for the attachment-detachment rates of surfactant monomers to and from surfactant aggregates with matching the rates for small spherical premicellar aggregates and the rates for larger cylindrical micelles have been used. The full discrete spectrum of characteristic times of micellar relaxation and first three relaxation modes in their dependence on equilibrium monomer concentration have been computed with using the linearized form of the Becker-Döring difference equations. Overall time behavior of surfactant monomer and aggregate concentrations in micellisation and relaxation at large initial deviations from final equilibrium has been studied with the help of nonlinearized discrete Becker-Döring k

AB - A numerical description of micellisation and relaxation to an aggregate equilibrium in nonionic surfactant solution with spherical premicellar aggregates and stable polydisperse cylindrical micelles is presented for wide interval of total surfactant concentrations and initial conditions. The Smoluchowsky-type model for the attachment-detachment rates of surfactant monomers to and from surfactant aggregates with matching the rates for small spherical premicellar aggregates and the rates for larger cylindrical micelles have been used. The full discrete spectrum of characteristic times of micellar relaxation and first three relaxation modes in their dependence on equilibrium monomer concentration have been computed with using the linearized form of the Becker-Döring difference equations. Overall time behavior of surfactant monomer and aggregate concentrations in micellisation and relaxation at large initial deviations from final equilibrium has been studied with the help of nonlinearized discrete Becker-Döring k

KW - micelle kinetics relaxation

U2 - 10.1039/c3sm52460d

DO - 10.1039/c3sm52460d

M3 - Article

VL - 10

SP - 2619

EP - 2631

JO - Soft Matter

JF - Soft Matter

SN - 1744-683X

IS - 15

ER -

ID: 6992442