TY - JOUR

T1 - Kinetics of Aggregation and Relaxation in Micellar Surfactant Solutions

AU - Shchekin, A. K.

AU - Adzhemyan, L. Ts.

AU - Babintsev, I. A.

AU - Volkov, N. A.

N1 - Shchekin, A.K., Adzhemyan, L.T., Babintsev, I.A. et al. Kinetics of Aggregation and Relaxation in Micellar Surfactant Solutions. Colloid J 80, 107–140 (2018). https://doi.org/10.1134/S1061933X18020084

PY - 2018/3

Y1 - 2018/3

N2 - Theoretical results published in the last 17 years on the kinetics of aggregation and relaxation in micellar surfactant solutions have been reviewed. The results obtained by the analytical and direct numerical solution of the Becker–Döring kinetic equations and the Smoluchowski generalized equations, which describe different possible mechanisms of aggregation and relaxation on all time scales from ultrafast relaxation while reaching the quasi-equilibrium in the region of subcritical molecular aggregates to the last stage of slow relaxation of micelles to the final aggregated state, have been considered in detail. The droplet model and the model linear with respect to aggregation numbers have been used for the work of aggregation to describe the dynamics of the rearrangement of micellar systems consisting of only spherical, only cylindrical, and coexisting spherical and cylindrical aggregates, with the dynamics being both linear and nonlinear with respect to deviations from equilibrium. The results of molecular simulation of the rearrangement kinetics of micellar systems subjected to initial disturbance have been reviewed.

AB - Theoretical results published in the last 17 years on the kinetics of aggregation and relaxation in micellar surfactant solutions have been reviewed. The results obtained by the analytical and direct numerical solution of the Becker–Döring kinetic equations and the Smoluchowski generalized equations, which describe different possible mechanisms of aggregation and relaxation on all time scales from ultrafast relaxation while reaching the quasi-equilibrium in the region of subcritical molecular aggregates to the last stage of slow relaxation of micelles to the final aggregated state, have been considered in detail. The droplet model and the model linear with respect to aggregation numbers have been used for the work of aggregation to describe the dynamics of the rearrangement of micellar systems consisting of only spherical, only cylindrical, and coexisting spherical and cylindrical aggregates, with the dynamics being both linear and nonlinear with respect to deviations from equilibrium. The results of molecular simulation of the rearrangement kinetics of micellar systems subjected to initial disturbance have been reviewed.

KW - кинетика

KW - мицеллообразование

KW - MOLECULAR-DYNAMICS SIMULATIONS

KW - ALKYL SULFONATE MICELLE

KW - CYLINDRICAL MICELLES

KW - SLOW RELAXATION

KW - MICELLIZATION KINETICS

KW - STRUCTURAL-PROPERTIES

KW - ACTIVATION BARRIER

KW - IONIC SURFACTANTS

KW - FOUNDATIONS

KW - SYSTEMS

UR - http://www.scopus.com/inward/record.url?scp=85044649215&partnerID=8YFLogxK

UR - http://link.springer.com/10.1134/S1061933X18020084

UR - http://www.mendeley.com/research/kinetics-aggregation-relaxation-micellar-surfactant-solutions

U2 - 10.1134/S1061933X18020084

DO - 10.1134/S1061933X18020084

M3 - Review article

VL - 80

SP - 107

EP - 140

JO - Colloid Journal

JF - Colloid Journal

SN - 1061-933X

IS - 2

ER -