Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Kerr effect in solutions of carbosilane dendrimers with terminal mesogenic groups. / Ryumtsev, E. I.; Evlampieva, N. P.; Lezov, A. V.; Ponomarenko, S. A.; Boiko, N. I.; Shibaev, V. P.
в: Liquid Crystals, Том 25, № 4, 1998, стр. 475-479.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Kerr effect in solutions of carbosilane dendrimers with terminal mesogenic groups
AU - Ryumtsev, E. I.
AU - Evlampieva, N. P.
AU - Lezov, A. V.
AU - Ponomarenko, S. A.
AU - Boiko, N. I.
AU - Shibaev, V. P.
N1 - Funding Information: This reeaswasrsupcporthed by the RussniFoandaution of Fundamental Research (grants 96-03-33820 and 97-03-32704), INAPrSTjote96-9c22, EuropeaRnseeh arc O ce USARDSG-UK (grants 68171-97-M-5822) and Russian Research Program Ùniversities of Russia’ (grant 5178).
PY - 1998
Y1 - 1998
N2 - First results of investigations of electro-optical properties of liquid crystalline (LC) dendrimers in solution are presented. Measurements of electric birefringence (Kerr effect) and dielectric polarization of first generation carbosilane dendrimers with different ester linked terminal mesogenic groups (cholesteryl, cyanobiphenylyl and 4-methoxyphenyl benzoate) have been carried out using dilute solutions in CCl4. The results show that the dielectric polarization is proportional to the second power of the electric field in accordance with Kerr law. The Kerr constants calculated are close to those of the low molar mass analogues of the corresponding mesogenic groups. Thus the electric birefringence of the LC dendrimer solutions is mainly determined by the electro-optical properties of their terminal mesogenic groups oriented in the electric field independently of the main chain.
AB - First results of investigations of electro-optical properties of liquid crystalline (LC) dendrimers in solution are presented. Measurements of electric birefringence (Kerr effect) and dielectric polarization of first generation carbosilane dendrimers with different ester linked terminal mesogenic groups (cholesteryl, cyanobiphenylyl and 4-methoxyphenyl benzoate) have been carried out using dilute solutions in CCl4. The results show that the dielectric polarization is proportional to the second power of the electric field in accordance with Kerr law. The Kerr constants calculated are close to those of the low molar mass analogues of the corresponding mesogenic groups. Thus the electric birefringence of the LC dendrimer solutions is mainly determined by the electro-optical properties of their terminal mesogenic groups oriented in the electric field independently of the main chain.
UR - http://www.scopus.com/inward/record.url?scp=0000341372&partnerID=8YFLogxK
U2 - 10.1080/026782998205985
DO - 10.1080/026782998205985
M3 - Article
AN - SCOPUS:0000341372
VL - 25
SP - 475
EP - 479
JO - Liquid Crystals
JF - Liquid Crystals
SN - 0267-8292
IS - 4
ER -
ID: 94258686