Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
Copper subgroup metal ions in the +1 oxidation state are classical candidates for aggregation via non-covalent metal-metal interactions, which are supported by a number of bridging ligands. The bridging phosphines, soft donors with a relatively labile coordination to coinage metals, serve as convenient and essential components of the ligand environment that allow for efficient self-assembly of discrete polynuclear aggregates. Simultaneously, accessible and rich modification of the organic spacer of such P-donors has been used to generate many fascinating structures with attractive photoluminescent behavior. In this work we consider the development of di- and polynuclear complexes of M(i) (M = Cu, Ag, Au) and their photophysical properties, focusing on the effect of phosphine bridging ligands, their flexibility and denticity.
Язык оригинала | английский |
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Страницы (с-по) | 6003-6033 |
Число страниц | 31 |
Журнал | Dalton Transactions |
Том | 50 |
Номер выпуска | 18 |
DOI | |
Состояние | Опубликовано - 14 мая 2021 |
ID: 77225916