Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Isotopic fractionation of methane and ethane hydrates between gas and hydrate phases. / Hachikubo, Akihiro; Kosaka, Tomoko; Kida, Masato; Krylov, Alexey; Sakagami, Hirotoshi; Minami, Hirotsugu; Takahashi, Nobuo; Shoji, Hitoshi.
в: Geophysical Research Letters, Том 34, № 21, L21502, 16.11.2007.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Isotopic fractionation of methane and ethane hydrates between gas and hydrate phases
AU - Hachikubo, Akihiro
AU - Kosaka, Tomoko
AU - Kida, Masato
AU - Krylov, Alexey
AU - Sakagami, Hirotoshi
AU - Minami, Hirotsugu
AU - Takahashi, Nobuo
AU - Shoji, Hitoshi
PY - 2007/11/16
Y1 - 2007/11/16
N2 - Isotopic fractionation of carbon and hydrogen in methane and ethane during the formation of gas hydrates was investigated. The gas hydrate samples were experimentally prepared in a pressure cell and isotopic compositions of both residual and hydrate-bound gases were measured. δD of hydrate-bound molecules of methane and ethane hydrates was several per mil lower than that of residual gas molecules in the formation processes, while there was no difference in the case of δ13C. These isotopic differences in δD are enough small for discussing the source types of hydrate-bound gases using the δ13C-δD diagram of Whiticar et al. [1986]. These results may provide useful insight into the formation process of gas hydrates.
AB - Isotopic fractionation of carbon and hydrogen in methane and ethane during the formation of gas hydrates was investigated. The gas hydrate samples were experimentally prepared in a pressure cell and isotopic compositions of both residual and hydrate-bound gases were measured. δD of hydrate-bound molecules of methane and ethane hydrates was several per mil lower than that of residual gas molecules in the formation processes, while there was no difference in the case of δ13C. These isotopic differences in δD are enough small for discussing the source types of hydrate-bound gases using the δ13C-δD diagram of Whiticar et al. [1986]. These results may provide useful insight into the formation process of gas hydrates.
UR - http://www.scopus.com/inward/record.url?scp=38549150401&partnerID=8YFLogxK
U2 - 10.1029/2007GL030557
DO - 10.1029/2007GL030557
M3 - Article
AN - SCOPUS:38549150401
VL - 34
JO - Geophysical Research Letters
JF - Geophysical Research Letters
SN - 0094-8276
IS - 21
M1 - L21502
ER -
ID: 47751207