Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Isomeric states of polar molecules on ionic surfaces : Electrostatic model and FTIR studies. / Storozhev, P. Yu; Yanko, V. S.; Tsyganenko, A. A.; Palomino, G. Turnes; Delgado, M. Rodríguez; Areán, C. Otero.
в: Applied Surface Science, Том 238, № 1-4 SPEC. ISS., 15.11.2004, стр. 390-394.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Isomeric states of polar molecules on ionic surfaces
T2 - Electrostatic model and FTIR studies
AU - Storozhev, P. Yu
AU - Yanko, V. S.
AU - Tsyganenko, A. A.
AU - Palomino, G. Turnes
AU - Delgado, M. Rodríguez
AU - Areán, C. Otero
PY - 2004/11/15
Y1 - 2004/11/15
N2 - Interaction of diatomic (polar) molecules with the surface of ionic solids is analysed by means of an electrostatic model which takes into account ion-dipole and ion-quadrupole interactions. This model was found to be capable of predicting the geometry of the adsorption complex, formation of isomeric states and relevant features of characteristic vibrational spectra. The theoretical model is demonstrated by considering the case of CO adsorbed on cation-exchanged zeolites for which a wealth of experimental data is available from both, vibrational spectroscopy and adsorption calorimetry. However, extension to other systems should be fairly straightforward.
AB - Interaction of diatomic (polar) molecules with the surface of ionic solids is analysed by means of an electrostatic model which takes into account ion-dipole and ion-quadrupole interactions. This model was found to be capable of predicting the geometry of the adsorption complex, formation of isomeric states and relevant features of characteristic vibrational spectra. The theoretical model is demonstrated by considering the case of CO adsorbed on cation-exchanged zeolites for which a wealth of experimental data is available from both, vibrational spectroscopy and adsorption calorimetry. However, extension to other systems should be fairly straightforward.
KW - Electrostatic interactions
KW - Isomeric states
KW - Localized adsorption
KW - Surface complexes
KW - Vibrational spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=4644370324&partnerID=8YFLogxK
U2 - 10.1016/j.apsusc.2004.05.242
DO - 10.1016/j.apsusc.2004.05.242
M3 - Article
AN - SCOPUS:4644370324
VL - 238
SP - 390
EP - 394
JO - Applied Surface Science
JF - Applied Surface Science
SN - 0169-4332
IS - 1-4 SPEC. ISS.
ER -
ID: 13733835