Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Two compounds containing isolated uranyl chromate and polychromate units were synthesized through room-temperature reactions of uranyl nitrate, chromium(VI) oxide, and 18-crown-6/15-crown-5 in aqueous solutions. Uranyl chromate with 18-crown-6 consists of neutral ∞ 0[(UO2)(CrO4)(H2O)3] units formed by the bidentate character of the edge sharing UrO5 bipyramid with only CrO4 and organic molecules and no additional crystallization water molecules. Uranyl polychromate with 15-crown-5 is the first inorganic compound in which [CrO4]2-, [Cr2O7]2-, and [Cr3O10]2- chromate groups are observed simultaneously.
Язык оригинала | английский |
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Страницы (с-по) | 5495-5498 |
Число страниц | 4 |
Журнал | European Journal of Inorganic Chemistry |
Том | 2014 |
Номер выпуска | 32 |
DOI | |
Состояние | Опубликовано - 2014 |
ID: 9144762