Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
Isocyanide metal complexes in catalysis. / Mahmudov, Kamran T.; Kukushkin, Vadim Yu; Gurbanov, Atash V.; Kinzhalov, Mikhail A.; Boyarskiy, Vadim P.; da Silva, M. Fátima C.Guedes; Pombeiro, Armando J.L.
в: Coordination Chemistry Reviews, Том 384, 01.04.2019, стр. 65-89.Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
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TY - JOUR
T1 - Isocyanide metal complexes in catalysis
AU - Mahmudov, Kamran T.
AU - Kukushkin, Vadim Yu
AU - Gurbanov, Atash V.
AU - Kinzhalov, Mikhail A.
AU - Boyarskiy, Vadim P.
AU - da Silva, M. Fátima C.Guedes
AU - Pombeiro, Armando J.L.
PY - 2019/4/1
Y1 - 2019/4/1
N2 - The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.
AB - The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.
KW - Homogeneous and heterogeneous catalysis
KW - Isocyanide metal complexes
KW - Metal-catalyzed and metal-mediated reactions
KW - Organic transformations
KW - COORDINATION CHEMISTRY
KW - COPPER-ISONITRILE COMPLEX
KW - PALLADIUM COMPLEXES
KW - SYNTHETIC REACTIONS
KW - TRANSFER HYDROGENATION
KW - CYCLIC-COMPOUNDS
KW - RADICAL-ADDITION
KW - TERT-ALKYL ISOCYANIDE
KW - STEREOSELECTIVE-SYNTHESIS
KW - INTRAMOLECULAR BIS-SILYLATION
UR - http://www.scopus.com/inward/record.url?scp=85060550008&partnerID=8YFLogxK
UR - http://www.mendeley.com/research/isocyanide-metal-complexes-catalysis
U2 - 10.1016/j.ccr.2019.01.002
DO - 10.1016/j.ccr.2019.01.002
M3 - Review article
AN - SCOPUS:85060550008
VL - 384
SP - 65
EP - 89
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
ER -
ID: 41786956