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IR-spectroscopic study of the binding isomerism of adsorbed molecules. / Tsyganenko, A. A.; Storozhev, P. Yu; Otero Areán, C.

в: Kinetics and Catalysis, Том 45, № 4, 07.2004, стр. 530-540.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Tsyganenko, AA, Storozhev, PY & Otero Areán, C 2004, 'IR-spectroscopic study of the binding isomerism of adsorbed molecules', Kinetics and Catalysis, Том. 45, № 4, стр. 530-540. https://doi.org/10.1023/B:KICA.0000038081.43384.56

APA

Tsyganenko, A. A., Storozhev, P. Y., & Otero Areán, C. (2004). IR-spectroscopic study of the binding isomerism of adsorbed molecules. Kinetics and Catalysis, 45(4), 530-540. https://doi.org/10.1023/B:KICA.0000038081.43384.56

Vancouver

Tsyganenko AA, Storozhev PY, Otero Areán C. IR-spectroscopic study of the binding isomerism of adsorbed molecules. Kinetics and Catalysis. 2004 Июль;45(4):530-540. https://doi.org/10.1023/B:KICA.0000038081.43384.56

Author

Tsyganenko, A. A. ; Storozhev, P. Yu ; Otero Areán, C. / IR-spectroscopic study of the binding isomerism of adsorbed molecules. в: Kinetics and Catalysis. 2004 ; Том 45, № 4. стр. 530-540.

BibTeX

@article{b727dd89032a4b76b2ddb920da914dff,
title = "IR-spectroscopic study of the binding isomerism of adsorbed molecules",
abstract = "This paper discusses the use of IR spectroscopy in the studies of isomerism in the binding of adsorbed molecules with a surface when a molecule may form several different surface species at the same site. Species whose geometry does not provide minimal adsorption energy can be considered as adsorption complexes in an excited state. The spectral manifestations of such a {"}steric excitation{"} are compared with the electronic and vibrational excitations of surface species. The {"}sterically excited{"} isomeric states existing in thermodynamic equilibrium with ordinary adsorption species are found and studied in detail. Examples are CO molecules bound through C and O atoms with metal cations in zeolites or with surface hydroxyl groups, the thiophene molecule via hydrogen bonding with silanol groups, and HD molecules dissociatively adsorbed on ZnO. A possible role of {"}sterically activated{"} isomeric states in catalysis is discussed.",
author = "Tsyganenko, {A. A.} and Storozhev, {P. Yu} and {Otero Are{\'a}n}, C.",
year = "2004",
month = jul,
doi = "10.1023/B:KICA.0000038081.43384.56",
language = "English",
volume = "45",
pages = "530--540",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - IR-spectroscopic study of the binding isomerism of adsorbed molecules

AU - Tsyganenko, A. A.

AU - Storozhev, P. Yu

AU - Otero Areán, C.

PY - 2004/7

Y1 - 2004/7

N2 - This paper discusses the use of IR spectroscopy in the studies of isomerism in the binding of adsorbed molecules with a surface when a molecule may form several different surface species at the same site. Species whose geometry does not provide minimal adsorption energy can be considered as adsorption complexes in an excited state. The spectral manifestations of such a "steric excitation" are compared with the electronic and vibrational excitations of surface species. The "sterically excited" isomeric states existing in thermodynamic equilibrium with ordinary adsorption species are found and studied in detail. Examples are CO molecules bound through C and O atoms with metal cations in zeolites or with surface hydroxyl groups, the thiophene molecule via hydrogen bonding with silanol groups, and HD molecules dissociatively adsorbed on ZnO. A possible role of "sterically activated" isomeric states in catalysis is discussed.

AB - This paper discusses the use of IR spectroscopy in the studies of isomerism in the binding of adsorbed molecules with a surface when a molecule may form several different surface species at the same site. Species whose geometry does not provide minimal adsorption energy can be considered as adsorption complexes in an excited state. The spectral manifestations of such a "steric excitation" are compared with the electronic and vibrational excitations of surface species. The "sterically excited" isomeric states existing in thermodynamic equilibrium with ordinary adsorption species are found and studied in detail. Examples are CO molecules bound through C and O atoms with metal cations in zeolites or with surface hydroxyl groups, the thiophene molecule via hydrogen bonding with silanol groups, and HD molecules dissociatively adsorbed on ZnO. A possible role of "sterically activated" isomeric states in catalysis is discussed.

UR - http://www.scopus.com/inward/record.url?scp=4444222830&partnerID=8YFLogxK

U2 - 10.1023/B:KICA.0000038081.43384.56

DO - 10.1023/B:KICA.0000038081.43384.56

M3 - Article

AN - SCOPUS:4444222830

VL - 45

SP - 530

EP - 540

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 4

ER -

ID: 13733780