Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Ion adsorption at the rutile-water interface : Linking molecular and macroscopic properties. / Zhang, Z.; Fenter, P.; Cheng, L.; Sturchio, N. C.; Bedzyk, M. J.; Předota, M.; Bandura, A.; Kubicki, J. D.; Lvov, S. N.; Cummings, P. T.; Chialvo, A. A.; Ridley, M. K.; Bénézeth, P.; Anovitz, L.; Palmer, D. A.; Machesky, M. L.; Wesolowski, D. J.
в: Langmuir, Том 20, № 12, 08.06.2004, стр. 4954-4969.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Ion adsorption at the rutile-water interface
T2 - Linking molecular and macroscopic properties
AU - Zhang, Z.
AU - Fenter, P.
AU - Cheng, L.
AU - Sturchio, N. C.
AU - Bedzyk, M. J.
AU - Předota, M.
AU - Bandura, A.
AU - Kubicki, J. D.
AU - Lvov, S. N.
AU - Cummings, P. T.
AU - Chialvo, A. A.
AU - Ridley, M. K.
AU - Bénézeth, P.
AU - Anovitz, L.
AU - Palmer, D. A.
AU - Machesky, M. L.
AU - Wesolowski, D. J.
PY - 2004/6/8
Y1 - 2004/6/8
N2 - An understanding of the solution-crystal interface that connects the actual molecular structures to the macroscopic properties, was obtained, by combining in situ synchrotron X-ray measurements on submerged rutile single crystal surfaces with ab inito calculations, molecular dynamic simulations, and macroscopic ion adsorption data. All X-ray, ab inito, molecular dynamics, and ion adsorption results were broadly compatible with a Stern-based description of EDL structure. All cations were found to be adsorbed as 'inner sphere' species bonded directly to surface oxygen atoms. A link between macroscopic manifestations of metal oxide surface charging and ion adsorption and the molecule-scale interfacial structures was established.
AB - An understanding of the solution-crystal interface that connects the actual molecular structures to the macroscopic properties, was obtained, by combining in situ synchrotron X-ray measurements on submerged rutile single crystal surfaces with ab inito calculations, molecular dynamic simulations, and macroscopic ion adsorption data. All X-ray, ab inito, molecular dynamics, and ion adsorption results were broadly compatible with a Stern-based description of EDL structure. All cations were found to be adsorbed as 'inner sphere' species bonded directly to surface oxygen atoms. A link between macroscopic manifestations of metal oxide surface charging and ion adsorption and the molecule-scale interfacial structures was established.
UR - http://www.scopus.com/inward/record.url?scp=3042538558&partnerID=8YFLogxK
U2 - 10.1021/la0353834
DO - 10.1021/la0353834
M3 - Article
AN - SCOPUS:3042538558
VL - 20
SP - 4954
EP - 4969
JO - Langmuir
JF - Langmuir
SN - 0743-7463
IS - 12
ER -
ID: 43151382