Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Investigation of the possibility of using water-based binders with conducting polymer for high-voltage LiNi0.5Mn1.5O4 cathodes. / Попов, Андрей Юрьевич; Каменский, Михаил Александрович; Неделько, Николай Максимович; Волков, Филипп Сергеевич; Seifollahamiri, Ali; Irajizad, Azam; Ghasemi, Shahnaz; Елисеева, Светлана Николаевна.
в: Electrochimica Acta, Том 540, 147200, 10.11.2025.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Investigation of the possibility of using water-based binders with conducting polymer for high-voltage LiNi0.5Mn1.5O4 cathodes
AU - Попов, Андрей Юрьевич
AU - Каменский, Михаил Александрович
AU - Неделько, Николай Максимович
AU - Волков, Филипп Сергеевич
AU - Seifollahamiri, Ali
AU - Irajizad, Azam
AU - Ghasemi, Shahnaz
AU - Елисеева, Светлана Николаевна
PY - 2025/11/10
Y1 - 2025/11/10
N2 - High-voltage LiNi₀.₅Mn₁.₅O₄ (LNMO) cobalt-free cathode material is considered a promising cathode for sustainable energy storage, mainly when fabricated into electrodes with water-soluble binders. Here, the influence of different binder types, including conventional polyvinylidene fluoride, water-soluble carboxymethyl cellulose (CMC) and conductive poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) with CMC on the electrochemical performance of commercial LiNi0.5Mn1.5O4-based cathode materials was evaluated through galvanostatic charge/discharge cycling (GCD) and cyclic voltammetry (CV). Applying a conductive binder with a low content enabled the highest capacity value of 137 mAh∙g−1 for LNMO at a current density of 0.1 C. The use of the composite water-soluble conductive binder CMC/PEDOT:PSS improved the electrochemical properties of the cathode compared to the cathode based on CMC alone. The results achieved with the CMC/PEDOT:PSS binder are comparable to those of PVDF, which suggests that water-soluble and eco-friendly binders may be a promising alternative for high-voltage cathodes. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry were utilized to estimate the diffusion coefficients of lithium.
AB - High-voltage LiNi₀.₅Mn₁.₅O₄ (LNMO) cobalt-free cathode material is considered a promising cathode for sustainable energy storage, mainly when fabricated into electrodes with water-soluble binders. Here, the influence of different binder types, including conventional polyvinylidene fluoride, water-soluble carboxymethyl cellulose (CMC) and conductive poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) with CMC on the electrochemical performance of commercial LiNi0.5Mn1.5O4-based cathode materials was evaluated through galvanostatic charge/discharge cycling (GCD) and cyclic voltammetry (CV). Applying a conductive binder with a low content enabled the highest capacity value of 137 mAh∙g−1 for LNMO at a current density of 0.1 C. The use of the composite water-soluble conductive binder CMC/PEDOT:PSS improved the electrochemical properties of the cathode compared to the cathode based on CMC alone. The results achieved with the CMC/PEDOT:PSS binder are comparable to those of PVDF, which suggests that water-soluble and eco-friendly binders may be a promising alternative for high-voltage cathodes. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry were utilized to estimate the diffusion coefficients of lithium.
KW - CMC/PEDOT:PSS
KW - Cathode materials
KW - LiNi0.5Mn1.5O4
KW - Lithium-ion batteries
KW - Water-soluble binder
UR - https://www.mendeley.com/catalogue/bde443da-36e5-37b5-b038-235cb6a1599d/
U2 - 10.1016/j.electacta.2025.147200
DO - 10.1016/j.electacta.2025.147200
M3 - Article
VL - 540
JO - Electrochimica Acta
JF - Electrochimica Acta
SN - 0013-4686
M1 - 147200
ER -
ID: 140054211